华南理工大学学报(自然科学版) ›› 2014, Vol. 42 ›› Issue (10): 36-43.doi: 10.3969/j.issn.1000-565X.2014.10.007

• 材料科学与技术 • 上一篇    下一篇

不同流场特性下的PS/HDPE共混物性能

殷小春 汤邦 曾文兵 杨智韬 瞿金平   

  1. 1.华南理工大学 聚合物新型成型装备国家工程研究中心//聚合物成型加工工程教育部重点实验室,广东 广州 510640;2. 湖北三江航天万峰科技发展有限公司,湖北 孝感 432000
  • 收稿日期:2014-06-16 修回日期:2014-07-03 出版日期:2014-10-25 发布日期:2014-10-01
  • 通信作者: 杨智韬(1981-),男,博士,副教授,主要从事新型聚合物成型装备研究 E-mail:meztyang@scut.edu.cn
  • 作者简介:殷小春(1975-),男,博士,副教授,主要从事高分子材料成型加工新理论与新装备研究;E-mail:mxcyin@163.com
  • 基金资助:

    NSFC-广东联合基金资助项目(U1201242);国家自然科学基金青年科学基金项目(51403068);华南理工大学中央高校基本科研业务费专项资金资助项目(2013ZZ0015,2014ZB0021).

Properties of PS/HDPE Blends with Different Flow Field Characteristics

Yin Xiao-chun Tang Bang Zeng Wen-bing Yang Zhi-tao Qu Jin-ping   

  1. 1. National Engineering Research Center of Novel Equipment for Polymer Processing//Key Laboratory of Polymer Processing Engineering of the Ministry of Education, South China University of Technology, Guangzhou 510640, Guangdong China; 2.Hubei Sanjiang Space Wan Feng Technology Development Co. Ltd., Xiaogan 432000, Hubei, China
  • Received:2014-06-16 Revised:2014-07-03 Online:2014-10-25 Published:2014-10-01
  • Contact: 杨智韬(1981-),男,博士,副教授,主要从事新型聚合物成型装备研究 E-mail:meztyang@scut.edu.cn
  • About author:殷小春(1975-),男,博士,副教授,主要从事高分子材料成型加工新理论与新装备研究;E-mail:mxcyin@163.com
  • Supported by:

    NSFC-广东联合基金资助项目(U1201242);国家自然科学基金青年科学基金项目(51403068);华南理工大学中央高校基本科研业务费专项资金资助项目(2013ZZ0015,2014ZB0021).

摘要: 介绍了动态拉伸形变支配的叶片式混合装置的结构及工作原理,在该混合装置及商品化的以剪切形变为主的Brabender转子密炼机上进行PS/HDPE熔融共混实验,分析了转子轴转速和混合时间对共混物力学性能、流变性能及微观形貌的影响。结果表明:与Brabender转子密炼机类似,叶片式混合装置制得的PS/HDPE共混物的拉伸强度随混合时间的延长和转子轴转速的升高先增加之后基本保持不变;与Brabender转子密炼机相比,叶片式混合装置的转子轴转速对共混物分散相粒径的影响较小,且转速相同时达到相同的分散相粒径叶片式混合装置需要的混合时间较短;随转子轴转速升高和混合时间延长,利用转子密炼机共混所得共混物表观黏度基本保持不变,而叶片混合装置共混得到的共混物表观黏度降低。叶片混合装置比Brabender转子密炼机的混合效率高,混合效果更好。

关键词: 叶片式混合装置, 动态拉伸形变, 拉伸强度, 表观黏度, 微观形貌

Abstract:

In the investigation, the structure and working principle of a vane compounder dominated by dynamic tensile deformation were introduced, and PS/HDPE melt blending experiments were conducted on the vane compounder and a commercial Brabender rotor internal mixer dominated by shear deformation. Then, the influences of the rotating speed and the mixing time on the mechanical property, rheological property and microstructure of the blends were discussed. The results show that (1) the tensile strength of the PS/HDPE blends molded by the vane compounder first increases and then keeps stable with the increases of the mixing time and the rotating speed, which is similar to those of the Brabender rotor internal mixer; (2) as compared with the Brabender rotor internal mixer, the rotating speed of the vane compounder has a smaller effect on the particle size of the dispersion phase of the blends, and the vane compounder needs a shorter time to achieve the same particle size of the dispersion phase at the same rotating speed; (3) the apparent viscosity of the blends molded by the Brabender rotor internal mixer remains unchanged with the increases of the mixing time and the rotating speed while that of the vane compounder decreases; and (4) the vane compounder shows a higher mixing efficiency and a better mixing effect in comparison with those of the Brabender rotor internal mixer.

Key words: vane compounder, dynamic tensile deformation, tensile strength, apparent viscosity, microstructure