华南理工大学学报(自然科学版) ›› 2005, Vol. 33 ›› Issue (6): 50-54.

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木素磺酸盐在煤—水界面的吸附性能

张延霖 邱学青 王卫星 杨东杰   

  1. 华南理工大学 化工与能源学院,广东 广州 510640
  • 收稿日期:2004-09-07 出版日期:2005-06-25 发布日期:2005-06-25
  • 通信作者: 张延霖(1975-),男,博士生,主要从事可再生资源利用与精细化工方面的研究. E-mail:linkerzhang@163.com
  • 作者简介:张延霖(1975-),男,博士生,主要从事可再生资源利用与精细化工方面的研究.
  • 基金资助:

    广东省科技计划资助项目(2003A3030102)

Adsorption Performance of Lignosulfonates on Coal-Water Interface

Zhang Yan-lin  Qiu Xue-qing  Wang Wei-xing  Yang Dong-jie   

  1. College of Chemical and Energy Engineering,South China Univ.of Tech.,Guangzhou 510640, Guangdong,China
  • Received:2004-09-07 Online:2005-06-25 Published:2005-06-25
  • Contact: 张延霖(1975-),男,博士生,主要从事可再生资源利用与精细化工方面的研究. E-mail:linkerzhang@163.com
  • About author:张延霖(1975-),男,博士生,主要从事可再生资源利用与精细化工方面的研究.
  • Supported by:

    广东省科技计划资助项目(2003A3030102)

摘要: 为了解木素磺酸盐作为添加剂对水煤浆成浆性能的影响,通过测定其在煤—水界面的吸附等温线研究了木素磺酸盐的相对分子质量、金属阳离子溶液及煤水悬浮液pH值、温度和搅拌时间对木素磺酸盐在煤—水界面吸附性能的影响.结果发现:木素磺酸盐的相对分子质量越高,吸附量越大;一价金属离子木素磺酸盐在煤表面的吸附更为容易,吸附量也较大;pH值、温度、搅拌时间均会影响木素磺酸盐在煤表面的吸附,是制浆中应该着重控制的参数.实验中还以不同相对分子质量木素磺酸盐的吸附为对象研究了其吸附类型,发现其吸附第一平台遵循Langmuir吸附模型,并初步探索了其吸附强度差的原因.

关键词: 木素磺酸盐, 煤&mdash, 水界面, 吸附性能

Abstract:

In order to understand the influence of surfactants,namely,lignosulfonates,on the preparation propertv of coal‘water slurry,the adsorption performance of lignosulfonates on coal-water interface was investigated bv mea-suring the adsorption isotherms,thus revealing the influences of the relative molecular masses of lignosulfonates.the metal cations,the pH and the temperature of coal-water suspension,as well as the stirring time.The resuIts show that the adsorption capacity increases with the increase in the relative molecular mass of lignosulfonate. and that univalent cation is helpful to the improvement of adsorption capacity because it can be more easilv adsorbed onto coal‘water interface.Moreover,it is indicated that the pH and the temperature of the SUSpension ,as well as the stiring time are important parameters to be controlled in the suspension preparation because they will greatlv influ-ence the adsorption of lignosulfonates on coal·water interface. Furtherm ore,the corresponding adsorption type was researched by the adsorption experiments of lignosulfonates with different relative molecular masses. It is then con-cluded that the first adsorption level follows the adsorption model of Langmuir.The reason for the weak adsorption intensity in experiments was also preliminarily discussed.

Key words: lignosulfonates, coal-water interface, adsorption perform ance