华南理工大学学报(自然科学版) ›› 2007, Vol. 35 ›› Issue (7): 88-92.

• 化学化工 • 上一篇    下一篇

干燥进出口温度对EVA 可再分散乳胶粉的影响

谢德龙 张心亚 杨波 陈焕钦   

  1. 华南理工大学 化工与能源学院,广东 广州 510640
  • 收稿日期:2006-12-27 出版日期:2007-07-25 发布日期:2007-07-25
  • 通信作者: 谢德龙(1982-),男,博士生,主要从事精细化工研究. E-mail:xied182@yahoo.com.cn
  • 作者简介:谢德龙(1982-),男,博士生,主要从事精细化工研究.
  • 基金资助:

    广东省经贸委产业技术创新项目(2006740023 )

Influences of Inlet and Outlet Drying Temperatures on Re-Dispersible EV A Polymer Powders

Xie De-long  Zhang Xin-ya  Yang Bo  Chen Huan-qin   

  1. School of Chemical and Energy Engineering , South China Univ. of Tech. , Guangzhou 510640 , Guangdong , China
  • Received:2006-12-27 Online:2007-07-25 Published:2007-07-25
  • Contact: 谢德龙(1982-),男,博士生,主要从事精细化工研究. E-mail:xied182@yahoo.com.cn
  • About author:谢德龙(1982-),男,博士生,主要从事精细化工研究.
  • Supported by:

    广东省经贸委产业技术创新项目(2006740023 )

摘要: 以聚乙烯醇(PVA) 为保护胶体、硅溶胶及无机粉体为抗结块剂,采用喷雾干燥法制备了乙烯-醋酸乙烯酯(EVA) 可再分散乳胶粉.讨论了进出口温度对产物性能的影响.试验结果表明:进出口温度对乳胶粉的外观、含水率、流动性、堆积密度、再分散及成膜性能和储存稳定性均有较大的影响;进出口温度升高,乳胶粉含水率降低,流动性提高,堆积密度下降;但进口温度过高,乳胶粉易发生烧结变性;合适的进(出)口温度为150 -180 ℃(72 -78 ℃ ). FTIR 测试结果显示,在进口温度为180℃时进行喷雾干燥,聚合物分子结构未发生明显改变.

关键词: 乙烯一醋酸乙烯酯, 可再分散乳胶粉, 性能, 喷雾干燥, 温度

Abstract:

Re-dispersible ethene-vinylacetate (EV A) polymer powders were prepared by means of spray drying , with polyvinyl alcohol (PV A) as the protective colloid and silica sol and inorganic powders as the anti -agglomerating agents. Then , the influence of the inlet and outlet temperatures on the performances of the prepared powders was investigated. Experimental results show that the inlet and outlet temperatures greatly influence the appearance ,water content , fluidity , stacking density , re-dispersibility , film performance and storage stability of the polymer powders , and that the water content and the stacking density decrease while the fluidity improves when increasing the inlet and outlet temperatures. It is also found that the appropriate inlet and outlet temperatures for spray drying are respectively 150 - 180℃ and 75 - 80 ℃, and that giving higher inlet temperature may result in the structure change of the powders. Moreover , the FfIR spectrum indicates that the mo1ecu1ar structure of the polymer powders after the spηdrying keeps unchanged at an inlet temperature of 180 ℃ .

Key words: ethene-vinyl acetate, re-dispersible polymer powder, performance, spray drying, temperature