华南理工大学学报(自然科学版) ›› 2009, Vol. 37 ›› Issue (8): 132-139.

• 材料科学与技术 • 上一篇    下一篇

内掺氯离子对钢筋锈蚀的影响及不同材料对氯离子的固化

谢燕 吴笑梅 樊粤明 余其俊 陈映云   

  1. 华南理工大学 材料科学与工程学院, 广东 广州 510641
  • 收稿日期:2009-01-07 修回日期:2009-02-25 出版日期:2009-08-25 发布日期:2009-08-25
  • 通信作者: 谢燕(1982-),女,博士生,主要从事水泥混凝土材料的研究. E-mail:xieyanscut@gmail.com
  • 作者简介:谢燕(1982-),女,博士生,主要从事水泥混凝土材料的研究.
  • 基金资助:

    广州市环保局科技攻关项目(B09-B2070040)

Influence of Doped Chloride Ions on Steel Corrosion and Solidification of Chloride Ions by Different Materials

Xie Yah  Wu Xiao-mei  Fan Yue-ming  Yu Qi-jun  Chen Ying-yun   

  1. School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China
  • Received:2009-01-07 Revised:2009-02-25 Online:2009-08-25 Published:2009-08-25
  • Contact: 谢燕(1982-),女,博士生,主要从事水泥混凝土材料的研究. E-mail:xieyanscut@gmail.com
  • About author:谢燕(1982-),女,博士生,主要从事水泥混凝土材料的研究.
  • Supported by:

    广州市环保局科技攻关项目(B09-B2070040)

摘要: 参考钢筋锈蚀快速试验法,通过测试试件的半电池电位和阳极极化曲线,研究了拌合时引入的不同种类氯盐、含氯原材料对钢筋锈蚀的影响及不同材料对氯离子的固化性能.结果表明:CaCl2对钢筋锈蚀的危害比NaCl大,掺CaCl2时较低的氯离子浓度和较小的自由氯离子含量即引起钢筋锈蚀;掺结皮料作混合材时,掺量大于等于20%会引起锈蚀;炉渣氯离子含量低,对钢筋锈蚀没有危害;有效铝酸盐含量高的水泥及矿渣、粉煤灰的加入均能提高对氯离子的固化能力,有效降低钢筋锈蚀的危害;当体系掺入混合材或其他组分时,阳极极化试验比半电池电位能更有效地反映发生钢筋锈蚀的情况.

关键词: 内掺, 氯离子, 钢筋锈蚀, 固化

Abstract:

Based on the half-cell potential and anodic polarization curves obtained via the fast steel corrosion test, the influences of different chloride salts and chlorin-containing materials on the steel corrosion are investigated, and the solidification of doped chloride ions by different materials is analyzed. The results indicate that  the influ- ence of CaCl2 on steel corrosion is more serious than that of NaCl as steel corrosion may occur at lower total chloride and free-chloride contents when it is doped with CaCl2;  buildups may lead to steel corrosion at a content of more than 20% ;  bottom ash does not induce steel corrosion due to its low chloride content;  the addition of cement, slag and fly ash with high effective aluminate content effectively solidifies chloride ions and reduces the steel corrosion; and  anodic polarization curves describe the steel corrosion better than half-cell potential when cement is mixed with admixtures and other compositions.

Key words: internal doping, chloride ion, steel corrosion, solidification