华南理工大学学报(自然科学版) ›› 2005, Vol. 33 ›› Issue (3): 9-12,27.

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Yb3+— Er3+共掺硼磷酸盐玻璃光谱性质的成分依赖性

谢智莹 邓再德 杨钢锋 孙家森   

  1. 华南理工大学 特种功能材料及制备新技术教育部重点实验室,广东 广州 510640
  • 收稿日期:2004-05-14 出版日期:2005-03-25 发布日期:2005-03-25
  • 通信作者: 谢智莹(1979-),女,硕士生,主要从事掺稀土特种玻璃和光纤的研究 E-mail:aaanancy2004@163.com
  • 作者简介:谢智莹(1979-),女,硕士生,主要从事掺稀土特种玻璃和光纤的研究
  • 基金资助:

    广东省自然科学基金资助项目(013013);广东省科技计划资助项目(2002B1 1604)

Compisition Dependence of Spectroscopic Properties of Yb3+-Er3+Co-ped Borophosphate Glass

Xie Zhi-ying  De Zai-de  yang Gang-feng  Sun Jia-sen   

  1. Key Laboratory of Specially Functional Materials and Advanced Manufacturing Technology,the Ministry of Education,South China Univ.of Teeh.,Guangzhou 510640,Guangdong,China
  • Received:2004-05-14 Online:2005-03-25 Published:2005-03-25
  • Contact: 谢智莹(1979-),女,硕士生,主要从事掺稀土特种玻璃和光纤的研究 E-mail:aaanancy2004@163.com
  • About author:谢智莹(1979-),女,硕士生,主要从事掺稀土特种玻璃和光纤的研究
  • Supported by:

    广东省自然科学基金资助项目(013013);广东省科技计划资助项目(2002B1 1604)

摘要: 以Yb3+- Er3+共掺的B2O3-P2O5-MO-R2O-AI2O3(M=Zn,Ca,Sr,Ba;R=Li,Na,K)玻璃系统为研究对象,分别分析了B2O3 的含量以及加入不同种类的碱金属和碱土金属氧化物对玻璃的光谱性质的影响.研究结果表明,随着B2O3含量的提高,玻璃的自发辐射跃迁几率降低,辐射寿命增长,但吸收截面、相应的积分吸收截面和发射截面减小,玻璃的折射率在B2O3含量为15%(摩尔分数)时达到极小值.随着修饰体阳离子场强的升高,吸收截面和发射截面有增大趋势.

关键词: Yb3+-Er3+共掺硼磷酸盐玻璃, B2O3, 光谱性质, 成分依赖性

Abstract:

The effects of B2O3 content and different modifiers (alkali metals and alkaline earth oxides)on the spectroscopic properties of Yb3+-Er3+co-doped B2O3-P2O5-MO-R2O-AI2O3(M=Zn,Ca,Sr,Ba;R=Li,Na,K)system were respectively analyzed.Th e results indicate that,with the increase in B2O3 content,the radiation lifetime increases,while the spontaneous emission probability,the absorption cross-section,the corresponding integral absorption cross-section and emission cross-section all decrease,that the refraction index reaches its minimum when the mole fraction of B2O3 is 15%, and also that the absorption cross-section and the emission cross-section increase with the electric field intensity of the modifier cation.

Key words: Yb3+-Er3+ co-doped borophosphate ass, boron oxide, spectroscopic property, compo sition dependence