华南理工大学学报(自然科学版) ›› 2005, Vol. 33 ›› Issue (12): 96-99.

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有机液及有机混合液非线性声参量表达式—— 基于声速一碰撞因子理论

卢义刚 张杨   

  1. 华南理工大学 物理科学与技术学院,广东 广州 510640
  • 收稿日期:2004-12-26 出版日期:2005-12-25 发布日期:2005-12-25
  • 通信作者: 卢义刚(1962-),副教授,主要从事声学研究 E-mail:phyiglu@ scut.edu.cn
  • 作者简介:卢义刚(1962-),副教授,主要从事声学研究

Expressions of Acoustic Nonlinearity Parameter of Organic Liquid and Organic Liquid M ixture:Derived from Ultrasonic Velocity-Collision Factor Theory

Lu Yi-gang  Zhang Yang   

  1. College of Physical Science and Technology,South China Univ.of Tech.,Guangzhou 510640,Guangdong,China
  • Received:2004-12-26 Online:2005-12-25 Published:2005-12-25
  • Contact: 卢义刚(1962-),副教授,主要从事声学研究 E-mail:phyiglu@ scut.edu.cn
  • About author:卢义刚(1962-),副教授,主要从事声学研究

摘要: 基于Schaaffs声速一碰撞因子理论,结合有关液体压力和温度对碰撞因子影响的研究结果,导出了有机液及有机混合液的非线性声参量表达式,该表达式给出了B/A参量与各组分的分子排斥力指数、热力学参量及外部温度、压力状态的关系.通过该表达式,不需知道各组分的B/A参量便能够预测混合液的B/A参量,反之,通过测定混合液的B/A参量,可以了解混合液的内部结构信息.

关键词: 非线性声参量, 声速, 有机液, 有机混合液, 碰撞因子

Abstract:

Based on Schaafs’ultrasonic velocity-collision factor theory and in view of the relationship between the collision factor and the temperature and pressure of liquid,this paper deduces the expressions of acoustic nonlinear-ity parameter in organic liquid and organic liquid mixture.These expressions reveal the relationships between B/A parameter and the aspects such as the molecular repulsion force exponent and thermodynamic parameter of each component,as well as the external temperature and pressure of the medium.Thus,the B/A parameter of organic liquid mixture can be predicted without knowing the B/A parameter of each component.In addition,the internal con-struction information of organic liquid mixture can also be obtained by measuring the B/A parameter of the mixture.

Key words: acoustic nonlinearity parameter, ultrasonic velocity, organic liquid, organic liquid mixture, collision factor