华南理工大学学报(自然科学版)

• 材料科学与技术 • 上一篇    下一篇

基于CPM模型的骨料级配设计对含锂渣无机人造石性能的影响

殷素红1   杨笑笑1 吕维希2 吕子洋2   

  1. 1.华南理工大学 材料科学与工程学院,广东 广州 510640;

    2.江西金基新材料有限公司,江西 宜春 331100


  • 发布日期:2026-01-30

Influence of Aggregate Grading Design Based on CPM Modal on the Properties of Inorganic Artificial Stone Containing Lithium Slag

YIN Suhong1  YANG Xiaoxiao1  LÜ Xiwei2  LÜ Ziyang2    

  1. 1. School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China;

    2. Jiangxi Jinji New Material Co. ,Ltd. , Yichun 331100, Jiangxi, China

  • Published:2026-01-30

摘要:

文中首次采用锂渣部分取代无机人造石中的矿物骨料并基于可压缩堆积模型(CPM模型)进行紧密堆积级配设计,探究其对无机人造石的抗压强度、抗折强度、密度、吸水率和收缩性能的影响。结果表明,锂渣部分替代石英砂并进行骨料级配最佳的组别,与未进行骨料级配的全石英砂组别和锂渣部分替代石英砂组别相比,28d抗压强度分别提高了13.7%和24.1%,28d抗折强度分别提高了27.3%和36.2%,这主要在于骨料级配提高了人造石结构的致密性;压汞法孔结构测试表明前者比后两者的孔隙率分别下降了40.88%和47.19%,BSE图像统计分析孔结构测试表明前者的介观孔隙率分别降低了58.1%和60.9%,从而使前者的密度分别提高了4.8%和5.3%,吸水率分别下降了62.9%和64.5%。由于锂渣中含有膨胀组分CaSO4,可降低人造石的收缩变形,锂渣部分替代石英砂组别比全石英砂组别的28d干燥收缩值下降5.0%,进行骨料级配后的锂渣部分替代石英砂组别的28d干燥收缩进一步下降8.5%。锂渣用于人造石骨料拓展了其资源化利用新途径,基于CPM模型骨料级配设计提供了一种人造石配合比设计新方法。

关键词: 锂渣, 无机人造石, 可压缩堆积模型, 骨料级配

Abstract:

This study is the first to employ lithium slag to partially replace mineral aggregates in inorganic artificial stone and carry out the design of compact packing grading based on the compressible packing model (CPM model) to investigate its effects on the compressive strength, flexural strength, density, water absorption and shrinkage properties of inorganic artificial stone. The results show that compared with the whole quartz sand group without aggregate grading and the lithium slag partially replacing quartz sand group, the compressive strength at 28 d increased by 13.7% and 24.1%, and the flexural strength in 28 d increased by 27.3% and 36.2%, respectively, mainly because the aggregate gradation improved the compactness of the artificial stone structure. The pore structure test of the mercury intrusion method showed that the porosity of the former decreased by 40.88% and 47.19%, respectively, and the pore structure test of BSE image statistical analysis showed that the mesoscopic porosity of the former was reduced by 58.1% and 60.9%, respectively, so that the density of the former increased by 4.8% and 5.3%, and the water absorption decreased by 62.9% and 64.5%, respectively. Since lithium slag contains the expansion component CaSO4, which can reduce the shrinkage and deformation of artificial stone, the 28 d drying shrinkage value of the lithium slag partially substituting quartz sand group is 5.0% lower than that of the whole quartz sand group, and the 28 d drying shrinkage of the lithium slag partially replacing quartz sand group after aggregate gradation is further reduced by 8.5%. The use of lithium slag in artificial stone aggregates expands its resource utilization methods, and provides a new method for the design of artificial stone mix ratio based on the CPM model aggregate gradation design.

Key words: lithium slag, inorganic artificial stone, Compressible Packing Model, aggregate grading