收稿日期: 2011-03-07
修回日期: 2011-04-08
网络出版日期: 2011-07-06
基金资助
广东省产学研项目( 2010B090400031) ; 国家"973”计划项目( 2010CB732206) ; 粤港关键领域重点突破项目( 2008A092000005)
Preparation of Calcium Carbonate Composite Filler Coated with Titanium Dioxide and Its Application in Papermaking
Received date: 2011-03-07
Revised date: 2011-04-08
Online published: 2011-07-06
Supported by
广东省产学研项目( 2010B090400031) ; 国家"973”计划项目( 2010CB732206) ; 粤港关键领域重点突破项目( 2008A092000005)
陈港 刘雅萍 方志强 . 钛白粉-碳酸钙复合填料的制备及在造纸中的应用[J]. 华南理工大学学报(自然科学版), 2011 , 39(8) : 87 -92 . DOI: 10.3969/j.issn.1000-565X.2011.08.016
A new kind of composite filler was prepared by coating the carrier of calcium carbonate,with titanium dioxide via the mechanochemical method. Then,the structure of the composite filler was characterized by using such parameters as oil-absorbed values,hiding power and particle size and by means of FT-IR and SEM,and the properties of the composite filler and its effect on paper were then investigated. The results show that( 1) the particle size of the composite filler is larger than the uncoated calcium carbonate; ( 2) the chemical bonds form between calcium carbonate and titanium dioxide and is of a good strength; ( 3) the hiding power and the oil absorption values of the composite filler are close to those of titanium dioxide; and( 4) at the same ash content,the optical properties and the physical strength of the paper filling with the composite filler are close to those of the paper filling with titanium dioxide,thus the composite filler being able to partly or wholly replace titanium dioxide.
Key words: titanium dioxide; coating; calcium carbonate; composite filler; mechanochemistry
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