收稿日期: 2010-12-06
修回日期: 2011-04-18
网络出版日期: 2011-07-06
基金资助
国家“973”计划项目( 2010CB732201 /4) ; 国家自然科学基金资助项目( 31070530) ; 广东省教育厅学科建设专项资金资助项目( N9100230) ; 华南理工大学基本科研业务费( 2009ZM0153)
Investigation into Physicochemical Properties of Xylan Derivatives with High Degree of Substitution
Received date: 2010-12-06
Revised date: 2011-04-18
Online published: 2011-07-06
Supported by
国家“973”计划项目( 2010CB732201 /4) ; 国家自然科学基金资助项目( 31070530) ; 广东省教育厅学科建设专项资金资助项目( N9100230) ; 华南理工大学基本科研业务费( 2009ZM0153)
彭新文 任俊莉 孙润仓 . 高取代度木聚糖衍生物的理化性质[J]. 华南理工大学学报(自然科学版), 2011 , 39(8) : 82 -86 . DOI: 10.3969/j.issn.1000-565X.2011.08.015
Bifunctional xylan derivatives ( XDs) with high degree of substitution were prepared from native xylan in wheat straw,with acrylamide as the etherifying agent,alkali as the catalyst,and butanol /water mixture as the reaction system. Then,the structure of the products was characterized by means of 13C NMR. Moreover,the dynamic rheological behaviors and thermal stability of XDs and the native xylan were tested by using a parallel-plate rheometer
and a simultaneous thermal analyzer, respectively. The results show that,as compared with the native xylan,the shear-thinning phenomenon of XDs solution is significant,with relatively lower viscosity,storage modulus and loss modulus,that the storage modulus is higher than the loss modulus,and that the thermal stability of the xylan declines after the modification.
Key words: xylan; derivative; bifunctional groups; butanol; rheological property
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