收稿日期: 2009-07-01
修回日期: 2009-09-26
网络出版日期: 2010-04-25
基金资助
国家“863”计划项目(2007AA03Z433); 广东省重点科技攻关项目(2008A0302008); 广东省科技计划项目(2008B030302035); 广东省节能减排重大专项(2008A080800003); 华南理工大学自然科学青年基金资助项目
Effects of Deinking Mode on Pore Structure and Crystallization Property of Recycled Fiber
Received date: 2009-07-01
Revised date: 2009-09-26
Online published: 2010-04-25
Supported by
国家“863”计划项目(2007AA03Z433); 广东省重点科技攻关项目(2008A0302008); 广东省科技计划项目(2008B030302035); 广东省节能减排重大专项(2008A080800003); 华南理工大学自然科学青年基金资助项目
郭文杰 王艳 万金泉 马邕文 . 脱墨方式对二次纤维孔隙结构和结晶性能的影响[J]. 华南理工大学学报(自然科学版), 2010 , 38(4) : 23 -29 . DOI: 10.3969/j.issn.1000-565X.2010.04.005
X-ray diffraction and low-temperature nitrogen adsorption were adopted to investigate the pore structure and crystallization property of the fibers of old newspaper pulp(ONP) and deinking pulp with different deinking modes,and the fractal geometry was used to further analyze the pore structure of the fibers.The results indicate that(1) the BET specific surface area,BJH pore volume and BJH average pore size of the deinking fibers remain almost unchanged after a neutral,alkaline or enzymatic deinking process;(2) the fractal dimensions of the fibers before and after the deinking process are similar,which means that deinking modes have little effect on the pore structure of the fibers;(3) the crystallinity of the fibers decreases to 12.24%,6.12% or 0.77% after a neutral,alkaline or enzymatic deinking process,respectively;(4) the water retention value(WRV) increases after deinking,in an order of alkali deinkingneutral deinkingenzymatic deinking;and(5) after deinking,the beating degree and average length of the fibers slightly decrease while the content of fine fibers increases.
Key words: deinking; crystallinity; pore structure; fractal; recycled fiber
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