收稿日期: 2009-08-11
修回日期: 2009-10-26
网络出版日期: 2010-08-25
基金资助
国家科技支撑计划项目(2006BA032806-2)
Chlorine Dioxide Bleaching Reinforced by Alkaline Extraction and Corresponding ECF Bleaching Sequences for Wheat Straw Pulp
Received date: 2009-08-11
Revised date: 2009-10-26
Online published: 2010-08-25
Supported by
国家科技支撑计划项目(2006BA032806-2)
赵德清 陈克复 莫立焕 李军 徐峻 杨仁党 杨飞 . 碱抽提强化的麦草浆ClO2漂白及ECF漂白流程[J]. 华南理工大学学报(自然科学版), 2010 , 38(8) : 45 -50 . DOI: 10.3969/j.issn.1000-565X.2010.08.009
Four kinds of alkaline extraction approaches, including the conventional, the oxygen-reinforced, the H2O2-reinforced and the oxygen-and-H2O2-reinforced ones (E, E0, Ep and E0p) , were used to modify ClO2-delignified (D0) wheat straw pulp, and the modification effects of these four approaches on the subsequent bleaching stage (D1) were explored. In addition, various elemental chlorine-free (ECF) bleaching sequences, such as D0ED1, D0P, DoA/QP, D0EP, D0EpD1 and D0EpP, were comparatively investigated. The results indicate that ( 1 ) the modification effects of different alkaline extraction approaches on the residual lignin of Do stage are different from one other; (2) for the subsequent D1 stage, the bleachability of D1 pulp varies in an order of D0E0P 〉 D0Ep 〉 D0E0 〉 D0E; (3) in the D0ED1 bleaching sequences, the increase of ClO2 dosage in D1 stage results in the brightness enhancement in a certain degree, especially at an optimized ClO2 dosage of 0. 8% -1.0% ; (4) as compared with the other sequences, D0EpD1 and D0EpP sequences are both of better bleaching effect; and (5) with D0EpD1 and DoEpP bleaching sequences, the final brightness of bleached wheat straw pulp reaches 82.3% ISO and 83.8% ISO, respectively, which means that both D0EpD1 and DoEpP sequences are applicable to the ECF short-sequence bleaching of wheat straw pulp.
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