收稿日期: 2009-12-28
修回日期: 2010-04-29
网络出版日期: 2010-09-25
基金资助
国家自然科学基金资助项目(20646003); 广东省自然科学基金资助项目(07300767); 华南理工大学中央高校基本科研业务费专项资金资助项目(2009ZM0239)
Nanocellulose Whiskers as Thickening Rheological Agent for Waterborne Polyurethane Dispersion
Received date: 2009-12-28
Revised date: 2010-04-29
Online published: 2010-09-25
Supported by
国家自然科学基金资助项目(20646003); 广东省自然科学基金资助项目(07300767); 华南理工大学中央高校基本科研业务费专项资金资助项目(2009ZM0239)
叶代勇 周刘佳 . 纳米纤维素晶须用作水性聚氨酯的增稠流变剂[J]. 华南理工大学学报(自然科学版), 2010 , 38(9) : 63 -67,74 . DOI: 10.3969/j.issn.1000-565X.2010.09.012
Nanocellulose whisker(NCW) suspension was prepared via the acid-catalyzed hydrolysis and the pro-duct was characterized.Then,the effects of temperature and NCW content on the viscosity of the suspension were analyzed,and the Ostwade power equation model of the suspension was discussed,finding that the viscosity of NCW suspension increases with the NCW content,but it is insensitive to temperature.Moreover,the effects of temperature and NCW content on the rheological properties of waterborne polyurethane(WPU) dispersion mixed with NCW suspension were investigated.The results show that the addition of NCW in the WPU dispersion helps to decrease the viscous flow activation energy and improve the thixotropy of the mixed system,meaning that NCW is an effective thickening agent of WPU dispersion.
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