收稿日期: 2024-12-06
网络出版日期: 2025-06-30
基金资助
广西科技重大专项(桂科AA23023018);广西重点研发计划项目(桂科AB23026026)
Computational Model for Chloride Diffusion Coefficient in Concrete Considering the Influence of Cement Type and Strength
Received date: 2024-12-06
Online published: 2025-06-30
Supported by
the Guangxi Major Science and Technology Project(AA23023018);the Guangxi Key Research and Development Project(AB23026026)
通过对广源大样本RCM(氯离子快速迁移)试验数据的回归分析确定水泥品类因子,并据此建立考虑水泥类型和强度等级影响的混凝土氯离子扩散系数计算模型,以此克服传统计算模型难以通过不同试验室交叉检验的缺陷。首先,基于来源于70个不同试验室的179组混凝土RCM试验数据形成的氯离子扩散系数的广源大样本试验数据库,通过回归分析确定水胶比、水泥类型及强度等级对氯离子扩散系数的影响规律;然后,利用广源大样本试验数据和两相回归法,在混凝土氯离子扩散系数计算模型中引入水泥品类因子,并确定其取值,从而建立考虑水泥类型和强度等级影响的氯离子扩散系数模型;最后,与传统模型开展对比分析,并利用非建模试验数据进行验证。结果表明:与传统的单源小样本模型相比,广源大样本模型可将模型对试验数据的拟合度提升19.6%;水泥品类因子能够合理反映水泥类型和强度等级的影响,据此建立的扩散系数模型与传统模型相比,可进一步将模型加权平均误差和变异系数分别降低32.0%和25.0%,从而大幅提升了模型的预测精度和适应性。
关键词: 混凝土; 水泥品类因子; 氯离子扩散系数; 氯离子快速迁移(RCM); 广源大样本
朱恩 , 杨绿峰 . 考虑水泥品类影响的混凝土氯离子扩散系数模型[J]. 华南理工大学学报(自然科学版), 2025 , 53(12) : 153 -160 . DOI: 10.12141/j.issn.1000-565X.240573
To address the limitations of traditional models in cross-laboratory validation, this study proposes a chloride diffusion coefficient model for concrete that incorporates a cement type factor, accounting for the influence of cement type and strength grade. The model is developed through regression analysis of multi-source large-sample Rapid Chloride Migration (RCM) test data. Firstly, a comprehensive database of 179 RCM test datasets from 70 laboratories was established to analyze the effects of water-binder ratio, cement type, and strength grade on the chloride diffusion coefficient via regression. Furthermore, the cement type factor was introduced into the computational model using a two-phase regression method, and its value was determined based on the multi-source large-sample data. Finally, comparative analyses with traditional models and validation using independent test data were conducted. The results show that the proposed multi-source large-sample model improves the fitting accuracy to experimental data by 19.6% compared to conventional mono-source small-sample models. The cement type factor effectively captures the combined influence of cement type and strength, reducing the weighted average error and coefficient of variation by 32.0% and 25.0%, respectively, thereby significantly enhancing the model’s predictive precision and adaptability.
| [1] | YANG L F, LONG F, CHEN J,et al .Improved rapid chloride migration test for chloride diffusion coefficient of concrete based on the image processing technique[J].Journal of Testing and Evaluation,2023,51(6):4068-4082. |
| [2] | HASAN T M, ALLENA S, GILBERT L .Rapid chloride penetration test:an evaluation of corrosion resistance in ultra-high performance concrete[J].Journal of Building Engineering,2024,82:108317/1-13. |
| [3] | 混凝土结构耐久性设计与施工指南(2005修订版):CCES 01—2005 [S]. |
| [4] | GEHLEN C, LUDWING H M, TOLMAN F .DURACRETE R7:Compliance testing for probabilistic design purposes evaluation report[R].Arnhem:[s.n.],1998:34-37. |
| [5] | 普通混凝土长期性能和耐久性能试验方法标准: [S]. |
| [6] | Concrete, mortar and cement-based repair materals:chloride migration coefficient from non-steady-state migration experiments:N [S]. |
| [7] | YING J W, DENG C Y, QIAN S T,et al .Effect of water-to-binder ratio on chloride ion diffusion in concrete under continuous biaxial compression[J].Construction and Building Materials,2024,416:135308/1-13. |
| [8] | BOGAS J A, GOMES A S .Non-steady-state accelerated chloride penetration resistance of structural lightweight aggregate concrete[J].Cement and Concrete Composites,2015,60:111-122. |
| [9] | 金伟良,薛文,陈驹 .海岸及近海混凝土材料耐久性设计指标的影响参数分析[J].建筑结构学报,2011,32(12):86-97. |
| JIN Weiliang, XUE Wen, CHEN Ju .Effecting coefficients for concrete structure durability design index [J].Journal of Building Structures,2011,32 (12):86-97. | |
| [10] | LAY S, SCHIEBL P, CAIRNS J .Service life models:instructions on methodology and application of models for the prediction of the residual service life for classified environmental loads and types of structures in Europe [R].Munich:Technical University of Munich,2003:72-74. |
| [11] | THOMAS M D A, BENTZ E C .Life 365:computer program for predicting the service life and life-cycle costs of reinforced concrete exposed to chlorides[R].Michigan:ACI Committee 365,2002:12-56. |
| [12] | 赵尚传 .氯盐环境下非承载力因素对受弯构件可靠性的影响[J].公路,2003(9):12-17. |
| ZHAO Shang-chuan .The influence of non-bearing elements on the reliability of flexural members in chloride corrosion environment[J].Highway,2003(9):12-17. | |
| [13] | 吴丽君,邓德华,曾志,等 .RCM法测试混凝土氯离子渗透扩散性[J].混凝土,2006(1):100-103. |
| WU Li-jun, DENG De-hua, ZENG Zhi,et al .RCM testing the penetration and diffusion of chloride ion in concrete[J].Concrete,2006(1):100-103. | |
| [14] | CHEN J W, TIAN C, WEI X S .Experimental and simulation study on chloride permeability in cement paste[J].Construction and Building Materials,2020,262:120600/1-7. |
| [15] | RAMEZANIANPOUR A A, POURKHORSHIDI A R, SOBHANI J,et al .Durability of concrete containing blended cements in harsh marine environments:18 years exposure study[J].Construction and Building Materials,2021,299:123863/1-15. |
| [16] | VENQUIARUTO S, da SILVA L B, MOLIN D C C DAL .Influence of preloading-induced microcracking on the durability of concrete produced with different types of cement[J].Construction and Building Materials,2018,189:777-786. |
| [17] | 杨绿峰,周明,陈正,等 .基于强度和抗氯盐耐久性指标的混凝土配合比设计及试验研究[J].土木工程学报,2016,49(12):65-74. |
| YANG Lufeng, ZHOU Ming, CHEN Zheng,et al .Design and experiment of concrete mix proportion based on indices of strength and durability in chloride environment[J].China Civil Engineering Journal,2016,49(12):65-74. | |
| [18] | YU B, MA Q, HUANG H C,et al .Probabilistic prediction model for chloride diffusion coefficient of concrete in terms of material parameters[J].Construction and Building Materials,2019,215(10):941-957. |
| [19] | YANG L F, CAI R, YU B .Modeling of environmental action for submerged marine concrete in terms of surface chloride concentration[J].Structural Concrete,2018,19(5):1512-1520. |
| [20] | 通用硅酸盐水泥: [S]. |
| [21] | 通用硅酸盐水泥: [S]. |
| [22] | YANG L F, ZHU E, WEI Y C .Experimental data for chloride diffusion coefficient of concrete by rapid chloride migration test[DB/OL].(2023-07-25)[2025-01-15].. |
| [23] | GAO Y, SCHUTTER G D, YE G,et al .The ITZ microstructure,thickness and porosity in blended cementitious composite:effects of curing age,water to binder ratio and aggregate content[J].Composites Part B:Engineering,2014,60:1-13. |
| [24] | LIU J, LIU J Y, FAN X,et al .Experimental analysis on water penetration resistance and micro properties of concrete:effect of supplementary cementitious materials,seawater,sea-sand and water-binder ratio[J].Journal of Building Engineering,2022,50:104153/1-25. |
| [25] | HOOTON R D, TITHERINGTON M P .Chloride resistance of high-performance concretes subjected to accelerated curing[J].Cement and Concrete Research,2004,34 (9):1561-1567. |
| [26] | 杨绿峰,陈俊武,赵家琦,等 .混凝土RCM试验分析的面均法研究[J].土木工程学报,2020,53(12):22-28. |
| YANG Lufeng, CHEN Junwu, ZHAO Jiaqi,et al .Area average method for RCM test of concrete[J].China Civil Engineering Journal,2020,53(12):22-28. | |
| [27] | SIDERIS K K, TASSOS C, CHATZOPOULOS A,et al .Mechanical characteristics and durability of self compacting concretes produced with ladle furnace slag[J].Construction and Building Materials,2018,170:660-667. |
| [28] | LOLLINI F, REDAELLI E, BERTOLINI L,et al .Effects of Portland cement replacement with limestone on the properties of hardened concrete[J].Cement and Concrete Composites,2014(46):32-40. |
| [29] | GLINICKI M A, Jó?WIAK-NIED?WIEDZKA D, GIBAS K,et al .Influence of blended cements with calcareous fly ash on chloride ion migration and carbonation resistance of concrete for durable structures[J].Materials,2016,9(1):18/1-15. |
| [30] | HASHOLT M T, JENSEN O M .Chloride migration in concrete with super absorbent polymers[J].Cement and Concrete Composites,2015(55):290-297. |
| [31] | NANUKUTTAN S V, BASHEER P A M, MCCARTER W J,et al .The performance of concrete exposed to marine environments: predictive modelling and use of laboratory/on site test methods[J].Construction and Building Materials,2015(93):831-840. |
/
| 〈 |
|
〉 |