材料科学与技术

复合改性沥青密封胶的组成优化及性能研究

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  • 长安大学 材料科学与工程学院,陕西 西安 710064
夏慧芸(1981-),女,博士,副教授,主要从事交通功能材料研究。

收稿日期: 2022-08-22

  网络出版日期: 2022-11-16

基金资助

浙江省交通厅科技项目(2021012);长安大学中央高校基本科研业务费专项资金资助项目(300102310301)

Research on Composition Optimization and Performance of Composite Modified Asphalt Sealant

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  • College of Materials Science and Engineering,Chang’an University,Xi’an 710064,Shaanxi,China
夏慧芸(1981-),女,博士,副教授,主要从事交通功能材料研究。

Received date: 2022-08-22

  Online published: 2022-11-16

Supported by

the Science and Technology Project of Zhejiang Provincial Transportation Department(2021012);the Special Fund for Basic Scientific Research of Central Universities of Chang’an University(300102310301)

摘要

改性沥青类密封胶修补效果优异、生产成本较低,已被广泛应用于裂缝修补,但仍存在黏结性、柔韧性和耐久性不足的问题。热塑性硫化硅橡胶(TPSiV)兼具有硅橡胶结构稳定、耐候性佳和热塑性聚氨酯高强度、高弹性等优势,表现出优异的黏结性、耐久性、柔韧性以及高低温稳定性。本研究以90#基质沥青为主要原料,首先采用糠醛抽出油(FEO)对TPSiV进行预溶胀处理,再采用高速剪切法,通过添加苯乙烯-丁二烯-苯乙烯(SBS)、废旧胶粉(CR)、CaCO3等改性剂,制备得到一系列高效复合改性沥青密封胶。系统研究SBS、TPSiV、CR掺量和CR粒径对改性沥青密封胶各项性能的影响,最终通过密封胶全套的路用指标对配方进行验证。采用软化点差值法表征了该密封胶的热储存稳定性,用荧光显微镜和扫描电子显微镜观察了TPSiV和TPSiV改性沥青的微观结构,采用傅里叶红外光谱(FTIR)对沥青改性前后的红外光谱进行了表征。结果表明:SBS掺量的增大显著提高了其高温性能,推荐掺量为3%;TPSiV提高了密封胶的柔韧性和粘结性,最佳掺量为3%;随着CR粒径减小,高温性能提高,低温性能下降,选择40目作为最佳粒径;随着CR掺量增加,改性沥青高温性能得到改善,最佳掺量为22%。该密封胶最佳配方SBS∶TPSiV∶CR∶CaCO3∶FEO质量比5∶3∶22∶5∶3,满足储存稳定性要求;TPSiV具有粗糙的表面结构,表面附着有硅橡胶微粒,有利于后期与沥青粘附,且TPSiV在复合改性沥青中分散均匀,TPSiV复合改性沥青中化学改性和物理改性同时存在。

本文引用格式

夏慧芸, 杨浩田, 卢昌杰, 等 . 复合改性沥青密封胶的组成优化及性能研究[J]. 华南理工大学学报(自然科学版), 2023 , 51(6) : 136 -145 . DOI: 10.12141/j.issn.1000-565X.220540

Abstract

Modified asphalt sealant has excellent repair effect and low production cost, and has been widely used in crack repair, but there are still problems such as insufficient adhesion, low flexibility and low durability. Thermoplastic vulcanized silicone (TPSiV) has the advantages of silicone rubber such as stable structure, good weather resistance, high strength and high elasticity of thermoplastic polyurethane, showing excellent adhesion, durability, flexibility and high and low-temperature stability. In this study, 90# matrix asphalt was used as the main raw material. Firstly, furfural extraction oil (FEO) was used to pre-swelling TPSiV, and then high-speed shear method was used to prepare a series of high efficiency composite modified asphalt sealant by adding styrene-butadiene-styrene (SBS), waste rubber powder (CR), CaCO3 and other modifiers. The effects of SBS, TPSiV, CR content and CR particle size on the properties of modified asphalt sealant were systematically studied. Finally, the formula was verified through the indicators of the whole set of sealant. The thermal storage stability of the sealant was characterized by softening point difference method. The microstructure of TPSiV and TPSiV modified asphalt was observed by fluorescence microscope and scanning electron microscope. The IR spectra of asphalt before and after modification were characterized by Fourier infrared spectroscopy (FTIR).The results show that the increase of SBS content significantly improves its high temperature performance, and the best dosage is 3%. TPSiV improves the flexibility and cohesiveness of sealant, and the best dosage is 3%. With the decrease of CR particle size, the high-temperature performance is improved, while the low-temperature performance is decreased. The optimal particle size is 40 mesh. With the increase of CR content, the high-temperature performance of modified asphalt is improved, and the best dosage is 22%. The best sealant formula SBS∶TPSiV∶CR∶CaCO3∶FEO mass ratio is 5∶3∶22∶5∶3, which meets the requirements of storage stability. TPSiV has a rough surface structure and the surface attached with silicone rubber particles is conducive to its adhesion to asphalt, and TPSiV disperses evenly in the composite modified asphalt. Chemical modification and physical modification of TPSiV compound modified asphalt exist simultaneously.

参考文献

1 ZHANG H, SHENG X, WANG S,et al .Effects of different modifiers on thermal stability,constituents and microstructures of asphalt-based sealant[J].Journal of Thermal Analysis and Calorimetry2020142(3):1183-1192.
2 杜素军 .SBS/轻质碳酸钙/大豆油复合改性沥青灌缝胶性能研究[J].中国胶粘剂202130(4):59-62.
  DU Sujun .Study on performance of pouring sealant for asphalt modified by SBS/light calcium carbonate/soybean oil composite[J],China Adhesives202130(4):59-62.
3 王虎 .沥青路面高性能裂缝处治材料研发及应用[D].重庆:重庆交通大学,2019
4 高阳 .橡胶改性沥青灌缝材料开发与性能研究[D].重庆:重庆交通大学,2019
5 马玉林 .橡胶粉-SBS复合改性灌缝材料制备工艺及其高温流变性能研究[D].长春:吉林大学,2021
6 LUO Y M, GUO H Y, WANG Z J,et al .Effects of dioctyl phthalate on performance of asphalt sealant[J].Advances in Materials Science and Engineering20222022:1-12.
7 苏银强,刘玉梅,汪国贤,等 .表面氧化胶粉-纳米SiO2复合改性沥青性能研究[J].公路交通科技202239(3):1-8,29.
  SU Yinqiang, LIU Yumei, WANG Guoxian,et al .Study on properties of surface oxidized crumb rubber and nano-SiO2 composite modified asphalt[J].Journal of Highway and Transportation Science and Technology202239(3):1-8,29.
8 GONG Y, WU S, ZHANG Y,et al .Investigation of the high-temperature and rheological properties for asphalt sealant modified by SBS and rubber crumb[J].Polymers (Basel)202214(13):2558/1-17.
9 于晓晓,李彦伟,蔡斌,等 .胶粉改性沥青研究进展:从分子到工程[J].合成橡胶工业202245(1):2-12.
  YU Xiaoxiao, LI Yanwei, CAI Bin,et al .Advance in crumb rubber modified asphalt:from molecule to engineering[J].China Synthetic Rubber Industry202245(1):2-12.
10 GONG Y, PANG Y, HE F,et al .Investigation on preparation and properties of crack sealants based on CNTs/SBS composite-modified asphalt[J].Materials202114(16):4569/1-18.
11 ZHAO Z, WANG L, WANG W,et al .Experimental investigation of the high-temperature rheological and aging resistance properties of activated crumb rubber powder/SBS composite-modified asphalt[J].Polymers (Basel)202214(9):1905/1-16.
12 赵旭 .基于胶粉与SBS复合改性的灌缝胶实验研究[D].保定:河北大学,2018
13 申忠硕,秦刚,张震,等 .硅橡胶粉改性沥青制备及性能研究[J].公路201863(6):244-248.
  SHEN Zhongshuo, QIN Gang, ZHANG Zhen,et al .Preparation and research on performance of asphalt modified by silicone rubber powder[J].Highway201863(6):244-248.
14 RASHED R A .Low-viscosity,silicone-modified penetrating asphalt sealer to eliminate water associated problems in asphalt pavements:US7179017 B2[P].2007-02-20.
15 AL-ANI T .Modification of asphalt mixture performance by rubber-silicone additive[J].Anbar Journal of Engineering Sciences20092(1):71-81.
16 AKBULUT H, GüRER C .Investigation of the performance of silicone rubber modified bitumen[J].Silicon202214(2022) :9721-9731.
17 秦威 .硅橡胶/聚氨酯热塑性硫化胶(TPSiV)及其共混物制备与性能的研究[D].北京:北京化工大学,2021
18 颜停博,冉旭,陈正雄 .聚氨酯/废胶粉复合改性沥青制备及性能研究[J].公路201964(6):214-219.
  YAN Tingbo, RAN Xu, CHEN Zhengxiong .Preparation and research on performance of asphalt modified by polyurethane and waste tire rubber[J].Highway201964(6):214-219.
19 公路工程沥青及沥青混合料试验规程: [S].
20 路面加热型密封胶: [S].
21 赵炜,李锋,刘林林,等 .沥青路面热灌型灌缝胶路用性能关键指标研究[J].现代交通技术202017(1):9-12.
  ZHAO Wei, LI Feng, LIU Linlin,et al .Study on the key performance index of heated caulking adhesive for asphalt pavement[J].Modern Transportation Technology202017(1):9-12.
22 公路工程沥青及沥青混合料试验规程: [S].
23 路用废胎胶粉橡胶沥青:JT∕T 798—2019 [S].
24 赵勇 .高体感相容性有机硅热塑性硫化橡胶(TPV)的制备、结构与性能[D].北京:北京化工大学,2020
25 张欢 .聚氨酯改性沥青及其混合料路用性能研究[D].哈尔滨:哈尔滨工业大学,2020
26 马嘉琛 .废胶粉-再生塑料复合改性高黏沥青制备及性能研究[D].西安:长安大学,2021
27 谢红飞 .SBS/胶粉复合改性沥青(SBS/CRCMA)制备与性能研究[D].乌鲁木齐:新疆农业大学,2021
28 曹雪娟,彭硕,丁勇杰,等 .聚氨酯改性沥青的研究进展[J].化工新型材料202149(10):213-218.
  CAO Xuejuan, PENG Shuo, DING Yongjie,et al .Research progress on polyurethane modified asphalt[J].New Chemical Materials202149(10):213-218.
29 金鑫,郭乃胜,尤占平,等 .聚氨酯改性沥青研究现状及发展趋势[J].材料导报201933(21):3686-3694.
  JIN Xin, GUO Naisheng, YOU Zhanping,et al .Research and development trends of polyurethane modified asphalt[J].Materials Review201933?(21):3686-3694.
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