材料科学与技术

不同养护温度下硫铝酸盐水泥的水化特性

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  • 同济大学 材料科学与工程学院∥先进土木工程材料教育部重点实验室,上海 201804
王中平( 1960-) 男,博士,副教授,博士生导师,主要从事水泥混凝土孔结构及其气渗性等研究

收稿日期: 2017-11-30

  修回日期: 2018-05-14

  网络出版日期: 2018-06-01

基金资助

国家重点研发计划项目( 2016YFB0303503) ; 国家自然科学基金资助项目( 51402216) ; 同济大学大型仪器设备开 放测试基金资助项目( 0002016046)

Hydration Features of Calcium Sulfoaluminate Cement at Different Curing Temperature

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  •  School of Materials Science and Engineering∥Key Laboratory of Advanced Civil Engineering Materials of the Ministry of Education,Tongji University,Shanghai 201804,China
王中平( 1960-) 男,博士,副教授,博士生导师,主要从事水泥混凝土孔结构及其气渗性等研究

Received date: 2017-11-30

  Revised date: 2018-05-14

  Online published: 2018-06-01

Supported by

Supported by the National Key Technology R & D Programs of China( 2016YFB0303503) and the National Natural Science Fundation of China( 51402216) 

摘要

研究了无水石膏掺量不同的硫铝酸盐水泥在 5 ℃、20 ℃和 40 ℃下的凝结时间、强 度发展、干燥收缩率及水化产物等. 结果表明: 无水石膏虽能促进水化产物钙矾石的生成, 但对硫铝酸盐水泥熟料水化的影响效果直接取决于养护温度———5 ℃ 下,无水石膏会显 著延缓早期水化,使凝结时间大幅延长,早期强度显著降低; 而20℃和40℃下作用效果相 反,因为石膏的掺入能有效抑制高温下钙矾石向单硫型水化硫铝酸钙的转变,所以 40 ℃ 下掺加石膏所得硫铝酸盐水泥砂浆的抗压强度较不掺时有不同程度的提升.

本文引用格式

王中平 赵亚婷 徐玲琳 . 不同养护温度下硫铝酸盐水泥的水化特性[J]. 华南理工大学学报(自然科学版), 2018 , 46(7) : 30 -38,46 . DOI: 10.3969/j.issn.1000-565X.2018.07.005

Abstract

A study has been performed on the setting time,compressive strength,drying shrinkage ratio and hydration products of calcium sulfoaluminate ( CSA) cements with different amounts of anhydrite at 5 ℃,20 ℃ and 40 ℃ . Results reveal that the effect on the hydration of calcium sulfoaluminate cement clinker depends directly on the curing temperature,although anhydrite can promote the formation of ettringite. At 5℃,anhydrite dramatically delays the early hydration so that the setting time is greatly extended and the early strength is significantly reduced, which is different from the condition at 20 ℃ and 40 ℃ . Because anhydrite can effectively inhibit the transition from ettringite to monosulfate at high curing temperature,the compressive strength of mortar with CSA cement cured at 40 ℃ is higher than that of CSA clinker.

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