食品科学与技术

脱色工艺对甜菜果胶色值及结构特性的影响

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  • 1. 华南理工大学 食品科学与工程学院,广东 广州 510640; 2. 华南理工大学 广东省天然产物绿色加工与产品安全实验室,广东 广州 510640
于淑娟(1955-),女,博士,教授,博士生导师,主要从事制糖工程、碳水化合物分子修饰研究.

收稿日期: 2017-03-03

  修回日期: 2017-08-30

  网络出版日期: 2017-10-31

基金资助

国家自然科学基金资助项目(31601423);广东省科技计划项目(2013B051000015);兵团科技攻关项目 (2016AB009);中国博士后科学基金资助项目(2016M590789)

Influence of Decolorization Procedures on Color Value and Molecular Structure of Sugar Beet Pectin

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  • 1.School of Food Science and Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China; 2.Guangdong Province Key Laboratory for Green Processing of Natural Products and Product Safety,South China University of Technology,Guangzhou 510640,Guangdong,China
于淑娟(1955-),女,博士,教授,博士生导师,主要从事制糖工程、碳水化合物分子修饰研究.

Received date: 2017-03-03

  Revised date: 2017-08-30

  Online published: 2017-10-31

Supported by

Supported by the National Natural Science Foundation of China(31601423),the Science and Technology Plan- ning Project of Guangdong Province(2013B051000015),the Achievements Transformation Fund Project(2016AB009) and China Postdoctoral Science Foundation(2016M590789)

摘要

为改善甜菜果胶颜色深、色泽暗的问题,文中采用透析、乙醇洗涤( 醇洗) 、H2O2 脱色方法对甜菜果胶进行脱色,并评价脱色工艺与脱色效果、甜菜果胶的分子结构、乳化特性的相关性.研究结果表明,透析法( 截留分子质量为 3000 ~14000 u) 和醇洗( 乙醇体 积分数为 60% ~80%) 两种脱色方法无法降低甜菜果胶的色值,而H2O2法则能显著降低 甜菜果胶的色值.考察了H2O2 用量、脱色时间对脱色效果的影响,发现甜菜果胶在 3% 的H2O2的碱性溶液中,室温脱色 0.5h 后,色差从 1.71 下降至-0.11,起初暗黄色的甜菜果 胶溶液变为澄清透亮的溶液.此外,甜菜果胶的结构在H2O2脱色作用下也发生变化,其半乳糖醛酸、中性糖、阿魏酸等含量降低,分子质量减小,且甜菜果胶的乳化活性下降到 66.7% ~75.0%. 综上所述,H2O2对甜菜果胶的脱色效果显著,这可能与H2O2破坏了甜菜果胶内源性呈色物质有关.然而,当H2O2的氧化效果过强时,甜菜果胶容易发生降解.

本文引用格式

于淑娟 李太鸿 郭晓明 王智明 艾超 郭筱兵 . 脱色工艺对甜菜果胶色值及结构特性的影响[J]. 华南理工大学学报(自然科学版), 2017 , 45(12) : 8 -13,77 . DOI: 10.3969/j.issn.1000-565X.2017.12.002

Abstract

In order to solve the dark color problem of sugar beet pectin (SBP),the methods of dialysis,alcohol leaching and H2O2decolorization were used to decolor the SBP solution,and the influence of the decoloring proce- dures on the decoloration effect as well as on the molecular structure and emulsifying property of the SBP was evalu- ated.It is found that neither the dialysis (MWCO is 3000 ~14000u) nor the alcohol leaching (the ethanol concen- tration is from 60% to 80%) has any influence on the color value of the SBP,while H2O2 can significantly reduce the SBP color value.Therefore,the influence of the H2O2 concentration and the bleaching time on the decoloriza- tion efficiency was investigated.The results show that,in an alkaline solution with 3% of H2O2 and after the bleaching at the room temperature for 0. 5h,the color value of the SBP decreases from 1. 71 to -0. 11,and the o- riginal dark yellow SBP solution turns into clear and bright solution.Furthermore,the H2O2 oxidation decolorization also changes the structure of the SBP,specifically,the contents of D-galacturonic acid,neutral sugar and ferulic acid in the SBP as well as the molecular mass of the SBP decrease,and the emulsifying activity of the SBP decrea- ses to 66. 7% ~75. 0% of the original.It is thus concluded that the decolorization effect of H2O2 on the SBP is sig- nificant,which can be attributed to the fact that the endogenous chromogenic material in the SBP is oxidized by H2O2 .However,the SBP is likely to be degraded when the oxidation of H2O2 is too strong.
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