材料科学与技术

有机酸侵蚀与水流冲刷耦合作用下水泥净浆的劣化评价

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  • 华南理工大学 材料科学与工程学院,广东 广州 510640
殷素红( 1971-) ,女,教授,博士生导师,主要从事水泥基复合材料、混凝土耐久性、低品位天然资源与工业废渣的高效利用等研究.

收稿日期: 2017-03-13

  修回日期: 2017-03-26

  网络出版日期: 2017-08-30

基金资助

国家自然科学基金国际( 地区) 合作与交流项目( 51561135012) ; 国家自然科学基金资助项目( 51372088) ; 华南理工大学和广东省水利水电科学研究院合作项目( D8152740)

Evaluation of Deterioration of Cement Paste Under Coupled Effects of Organic Acids and Scour

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  • School of Materials Science and Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China
殷素红( 1971-) ,女,教授,博士生导师,主要从事水泥基复合材料、混凝土耐久性、低品位天然资源与工业废渣的高效利用等研究.

Received date: 2017-03-13

  Revised date: 2017-03-26

  Online published: 2017-08-30

Supported by

Supported by the National Natural Science Foundation of Internatlonal( Regional) Cooperation and Exchange Program( 51561135012) and the National Natural Science Foundation of China( 51372083)

摘要

通过人工配制生物代谢酸侵蚀液,并设置2m/s 的水流速度,从侵蚀深度、氢氧化钙质量损失率、单位表面质量损失三方面进行水泥净浆劣化评价; 并通过对比单因素有机
酸浸泡侵蚀,研究了水流冲刷对净浆劣化的加速程度. 结果表明: 耦合作用下的侵蚀深度是单因素作用的2. 72 倍,耦合作用下的单位表面质量损失是单因素作用的3. 77 倍; 有机酸侵蚀和水流冲刷相互影响与促进,加剧了水泥基材料的劣化; 单位表面质量损失充分体现了耦合作用下有机酸侵蚀的化学作用和水流冲刷的物理作用,更适用于耦合作用下水泥基材料的劣化评价.

本文引用格式

殷素红 李榕 胡捷 黄浩良 . 有机酸侵蚀与水流冲刷耦合作用下水泥净浆的劣化评价[J]. 华南理工大学学报(自然科学版), 2017 , 45(9) : 96 -101,109 . DOI: 10.3969/j.issn.1000-565X.2017.09.014

Abstract

The deterioration of cement paste exposed to artificial organic acid solution involved in biological metabolism and a scour of 2m/s was evaluated,in terms of the erosion depth,the decrease of calcium hydroxide content and the loss of mass per unit area of sample surface.The acceleration of deterioration of cement paste caused by the scour of solution was investigated by comparing to the deterioration under static immersion.The results show that ( 1) the erosion depth and the loss of mass per unit area of sample surface under the coupled effects of organic acids and scour are 2. 72 times and 3. 77 times those in static organic acid solutions,respectively; ( 2) the coupled effects of the organic acids and the scour significantly accelerate the deterioration of cement paste; and ( 3) the loss of mass per unit area of sample surface fully reflects the chemical erosion effect of the organic acids and the physical effect of the scour,meaning that this index is suitable to evaluate the deterioration of cement-based materials.
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