材料科学与技术

抗坏血酸与茶多酚协同作用制备单层石墨烯

  • 陈港 ,
  • 朱朋辉 ,
  • 林东瀚 ,
  • 方志强
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  • 华南理工大学 制浆造纸工程国家重点实验室∥广东省特种纸与纸基功能材料工程技术研究中心,广东 广州 510640
陈港(1967-),男,教授,博士生导师,主要从事造纸技术与特种纸研究.

收稿日期: 2017-02-21

  修回日期: 2017-03-17

  网络出版日期: 2017-10-01

基金资助

国家重点基础研究发展计划(“973”计划)项目(2010CB732206);广东省部产学研专项资金技术前沿项目 (2013B090500071)

Preparation of Monolayer Graphene via Synergistic Action of Ascorbic Acid and Tea Polyphenols

  • CHEN Gang ,
  • ZHU Peng-Hui ,
  • LIN Dong-Han ,
  • FANG Zhi-Qiang
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  • State Key Laboratory of Pulp and Paper Engineering∥Guangdong Engineering Technology Research and Development Center of Specialty Paper and Paper-Based Functional Materials,South China University of Technology,Guangzhou 510640,Guangdong,China
陈港(1967-),男,教授,博士生导师,主要从事造纸技术与特种纸研究.

Received date: 2017-02-21

  Revised date: 2017-03-17

  Online published: 2017-10-01

Supported by

Supported by the National Program on Key Basic Research Project of China(973 Program,2010CB732206) and the Production,Education and Research Cooperative Project of Guangdong Province and the Ministry of Education (2013B090500071)

摘要

采用改良的 Hummers 法制备氧化石墨烯(GO),再用抗坏血酸(LAA)、茶多酚 (TP)和 LAA/TP 双组分还原体系作为还原剂,将氧化石墨烯还原成石墨烯(RGO),分别 进行导电性能测试、拉曼光谱分析、X 射线衍射分析以及 X 射线光电子能谱分析,并利用 扫描电镜、透射电镜以及原子力显微镜对 LAA/TP 双组分还原体系所制备的 RGO 的形貌 进行了表征. 结果表明,LAA/TP 双组分还原体系之间存在协同作用,其对 GO 的还原效果 优于单组分还原剂,所制备的 RGO 呈单层结构. 文中还对 LAA/TP 体系的协同作用机理 进行了阐释.

本文引用格式

陈港 , 朱朋辉 , 林东瀚 , 方志强 . 抗坏血酸与茶多酚协同作用制备单层石墨烯[J]. 华南理工大学学报(自然科学版), 2017 , 45(11) : 41 -47,2 . DOI: 10.3969/j.issn.1000-565X.2017.11.006

Abstract

Oxidized graphene oxide (GO) was prepared by means of the modified Hummers method,and it was re- duced to graphene (RGO) respectively by using ascorbic acid (LAA),tea polyphenols (TP) and the LAA/TP two-component reduction system as a reductant.Then,the conductivity,Raman spectroscopy,X-ray diffraction pattern and X-ray photoelectron spectroscopy of the obtained RGO were determined,and the morphology of the RGO prepared by LAA/TP was also characterized by means of the scanning electron microscopy,the transmission electron microscopy and the atomic force microscopy.The results show that there exists a synergistic effect between the two-component reduction system of LAA/TP,and the reduction effect of the system is better than that with only single component,and that the obtained RGO is of a monolayer structure.In addition,the mechanism of the syner- gistic effect between LAA and TP was also explained.
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