收稿日期: 2016-05-25
修回日期: 2016-11-16
网络出版日期: 2016-12-31
基金资助
国家自然科学基金资助项目( 21376099, 21546002) ; 石油化工联合基金资助项目( U1162120)
Properties of Asphalt Modified with Montmorillonite After a Modification by Isophorone Diisocyanate
Received date: 2016-05-25
Revised date: 2016-11-16
Online published: 2016-12-31
Supported by
Supported by the National Natural Science Foundation of China( 21376099, 21546002) and the Joint Foundation of Petroleum Processing( U1162120)
肖新颜 张登科 . 异佛尔酮二异氰酸酯改性蒙脱土改性沥青的性能[J]. 华南理工大学学报(自然科学版), 2017 , 45(2) : 116 -121 . DOI: 10.3969/j.issn.1000-565X.2017.02.016
Acidified montmorillonite ( HMMT) was modified with isophorone diisocyanate ( IPDI) ,and the obtained IPDI-HMMT was used as a chemical modifier to modify asphalt via melt blending.Then,the physical properties,UV aging resistance and thermal stability of the modified asphalt were investigated.The results show that ( 1) IPDI-HMMT grafted with —NCO can react with the hydroxy in asphalt to produce urethane and to form an exfoliated structure; ( 2) after the incorporation of IPDI-HMMT,the initial decomposition temperature of the modified asphalt increases by 9℃,the softening point is up to 57.0℃,and the segregation softening point difference,the mass change rate,the softening point increment and the residual penetration ratio all change more slightly than those of Na-MMT modified asphalt; and ( 3) the chemical reaction between IPDI-HMMT and asphalt enhances the interaction of the internal components,which helps to form a stable colloidal structure,so that IPDI-HMMT has greater enhancement effect on the asphalt performance than Na-MMT.
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