收稿日期: 2016-04-22
修回日期: 2016-09-20
网络出版日期: 2017-02-02
基金资助
国家自然科学基金重点项目( 31230057) ; 东莞市产学研合作项目( 201450911106)
Investigation into Sugar /Water Hot Gelatinization Mechanism of Chinese Yam Starch by Means of Integral Optical Density Method
Received date: 2016-04-22
Revised date: 2016-09-20
Online published: 2017-02-02
Supported by
Supported by the Key Program of National Natural Science Foundation of China( 31230057)
李倩 高群玉 . 累积光密度法研究山药淀粉的糖/水热糊化机制[J]. 华南理工大学学报(自然科学版), 2017 , 45(3) : 117 -124 . DOI: 10.3969/j.issn.1000-565X.2017.03.017
Firstly,an image analysis method,namely integral optical density ( IOD) method,was combined with the model of response difference of crystallite change ( MRDCC) to analyze the gelatinization property of Chinese yam starch.Then,XRD was adopted to discuss the crystalline structure of the starch.Finally,the effects of concentration and sugars variety on the gelatinization process were analyzed.The results demonstrate that ( 1) Chinese yam starch is in a C-type structure; ( 2) MRDCC shows double peaks that correspond to the gelatinization process of types B and A paramorph; ( 3) different sucrose concentrations as well as various monosaccharide,disaccharide,trisaccharide and tetrasccharide have different effects on the gelatinization process; ( 4) the inhibition effect due to sugar shows good correlation with dynamic hydration number,concretely,the more the equatorial hydroxyl number ( e-( OH) ) of sugar molecules,the stronger the inhibition effect; ( 5) sugar-water hydration effect is also related to the size and three-dimension structure of sugar molecules; and ( 6) a helical structure bonded through hydrogen bond is ideal for tetrasccharide because this structure weakens the hydratability,which means that the gelatinization inhibitiion effect of stachyose is smaller than that of raffinose.
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