收稿日期: 2016-03-07
修回日期: 2016-04-12
网络出版日期: 2016-10-04
基金资助
国家重点基础研究发展计划项目( 2012CB215302) ; 国家自然科学基金资助项目( 21376100) ; 国家国际科技合作专项( 2013DFA41670)
Chemical Structure of Enzymatic Hydrolysis Lignin from Corn Stover and its Application in Epoxy Composite
Received date: 2016-03-07
Revised date: 2016-04-12
Online published: 2016-10-04
Supported by
Supported by the National Program on Key Basic Research Project of China( 2012CB215302) , the National Natural Science Foundation of China( 21376100) and the Program for International S&T Cooperation Projects of China( 2013DFA41670)
郑大锋 李小康 于凡哲 陈然 . 玉米秸秆酶解木质素的化学结构及在环氧树脂中的应用[J]. 华南理工大学学报(自然科学版), 2016 , 44(11) : 26 -32 . DOI: 10.3969/j.issn.1000-565X.2016.11.005
The chemical structure of the enzymatic hydrolysis lignin ( EHL) from corn stover was characterized by means of UV spectroscopy,infrared spectroscopy,elemental analysis,headspace gas chromatography and potentiometric titration.It is found that there exist more substituents in the aromatic ring of the EHL,and β-O-4 linkage is of lower fracture degree,and that,the main structural unit was H-type,and the methoxy group,phenolic hydroxyl group and carboxyl contents of the EHL are respectively 6.50%,0.48% and 2.46%.By mixing the lignin and the epoxy resin to prepare the EHL /epoxy resin composite,it can be concluded that the EHL within a certain dosage can improve the tensile strength and bending strength of the EHL /epoxy resin composite,and the heat resistance of the EHL /epoxy resin composite increases with the EHL dosage,and that at 460℃,the residual amount of the epoxy resin composite containing 2.0% EHL is 8.3%,while the residual amount of pure epoxy resin is only 4.4%.The above-mentioned results show that the EHL can improve the mechanical properties and heat resistance of epoxy resin significantly,so it has a good application prospect in epoxy resin composites.
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