环境科学与技术

臭氧降解丁香酚的效果及动力学分析

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  • 华南理工大学 制浆造纸工程国家重点实验室,广东 广州 510640
李友明(1957-),男,教授,博士生导师,主要从事制浆造纸清洁生产技术、造纸化学品等的研究. E-mail:ymli3@ scut. edu. cn

收稿日期: 2015-08-06

  修回日期: 2016-02-01

  网络出版日期: 2016-05-03

基金资助

国家自然科学基金资助项目(21476091);广东省自然科学基金资助项目(2014A030310145);华南理工大学中央高校基本科研业务费专项资金资助项目(2014ZM0071)

Effect and Kinetics Analysis of Eugenol Degradation by Ozone

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  • State Key Laboratory of Pulp and Paper Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China
李友明(1957-),男,教授,博士生导师,主要从事制浆造纸清洁生产技术、造纸化学品等的研究. E-mail:ymli3@ scut. edu. cn

Received date: 2015-08-06

  Revised date: 2016-02-01

  Online published: 2016-05-03

Supported by

Supported by the National Natural Science Foundation of China(21476091)and the Natural Science Foundation of Guangdong Province(2014A030310145)

摘要

采用臭氧氧化法降解含水溶性木素衍生物丁香酚的模拟废水,考察了初始 pH值、丁香酚初始浓度、臭氧质量浓度和温度对臭氧氧化降解丁香酚过程中 CODCr 去除效果的影响,并对降解过程中 CODCr 去除反应的动力学进行研究. 结果表明:臭氧对丁香酚具有良好的氧化降解效果,在 pH = 11、丁香酚初始浓度为 1 mmol/L、臭氧质量浓度为24. 83mg/L、温度为25℃的条件下,臭氧降解丁香酚过程中的 CODCr 去除率可达67. 77%;臭氧氧化降解丁香酚过程中 CODCr 的去除反应符合两段拟一级反应动力学特征;采用幂指数方程分析反应动力学,可分别得到 0 ~10min 和 10 ~60min 反应时间内 CODCr 去除反应的动力学方程.

本文引用格式

陈景添 李友明 雷利荣 . 臭氧降解丁香酚的效果及动力学分析[J]. 华南理工大学学报(自然科学版), 2016 , 44(6) : 90 -97 . DOI: 10.3969/j.issn.1000-565X.2016.06.015

Abstract

Ozone was employed to degrade the water-soluble lignin-derived compound eugenol in a simulated wastewater system,and the effects of pH value,initial eugenol concentration,ozone mass concentration and reac- tion temperature on the CODCr removal as well as the corresponding kinetics were investigated.Experimental results show that (1) the ozonation process is effective in degrading eugenol; (2) the CODCr removal is up to 67. 77% after the ozonation with an initial eugenol concentration of 1 mmol/L and with an ozone mass concentration of 24. 83mg/L at 25℃ and pH 11; (3) the CODCr removal of eugenol accords well with the two-stage pseudo-first- order kinetics; and (4) the exponential function is effective in analyzing the ozonation kinetics and obtaining the kinetic models describing the CODCr removal within 0 ~10min and 10 ~60min,respectively.
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