材料科学与工程

石灰重构钢渣过程中的物相变化

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  • 1. 华南理工大学 材料科学与工程学院,广东 广州 510640; 2. 长江水利委员会长江科学院,湖北 武汉 430010
殷素红(1971-),女,博士,教授,主要从事水泥、混凝土材料和固体废弃物资源化利用研究.

收稿日期: 2015-11-09

  修回日期: 2015-12-07

  网络出版日期: 2016-05-03

基金资助

国家自然科学基金资助项目(51372088);中央级公益性科研院所基本科研业务费资助项目(CKSF2013042/JC)

Phase Change of Steel Slag During Reconstruction by Lime

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  • 1.School of Materials Science and Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China; 2.Changjiang River Scientific Research Institute,Changjiang Water Resources Commission,Wuhan 430010,Hubei,China
殷素红(1971-),女,博士,教授,主要从事水泥、混凝土材料和固体废弃物资源化利用研究.

Received date: 2015-11-09

  Revised date: 2015-12-07

  Online published: 2016-05-03

Supported by

Supported by the National Natural Science Foundation of China(51372088)

摘要

以石灰作为单一调节材料高温重构钢渣,利用 X 射线衍射、岩相分析、扫描电子显微镜研究了重构过程中钢渣的矿物组成及 RO 相的变化,并测定了重构钢渣的安定性和活性指数. 结果表明:RO 相在 CaO 作用下优先发生分解反应,其中的 FeO 随 CaO 掺量增加依次生成 Fe3O4 、CF(铁酸一钙)、C2 F(铁酸二钙)及 Ca2 (AlFe)O5 (铁铝酸钙)、C4 AF(铁铝酸四钙),其中的 MgO 部分以 MgO 晶体存在,部分固溶在硅酸盐相和液相中;当CaO/SiO2 摩尔比不够大时,原钢渣中的 C3 S(硅酸三钙)在重构过程中分解成 C2S(硅酸二钙);由于 CaO 优先与含量较高的铁元素反应,CaO/SiO2 摩尔比达到 3 时仍没有 C3S 生成,只有当与铁反应完全后多余的 CaO 才会与 C2S 反应生成 C3S;石灰重构钢渣不会产生安定性不良且胶凝活性明显提高.

本文引用格式

殷素红 高凡 郭辉 杨旭 . 石灰重构钢渣过程中的物相变化[J]. 华南理工大学学报(自然科学版), 2016 , 44(6) : 47 -52 . DOI: 10.3969/j.issn.1000-565X.2016.06.008

Abstract

Steel slag was reconstructed by using lime as the single controlling material at a high temperature,and XRD,petrographic analysis and SEM techniques were adopted to determine the mineral composition of the modified steel slag as well as the transformation of the RO phase in the modification process.Moreover,the stability and the activity index of the modified steel slag were tested.The results demonstrate that (1) the RO phase primarily reacts with CaO,in which FeO phase is decomposed into Fe3O4 ,CF (calcium ferrite),C2F (dicalcium ferrite), Ca2 (AlFe)O5 and C4 AF (tetracalcium alumino-ferrite) successively with the increase of CaO content,and a part of MgO phase exists in the form of MgO crystal,and the others behave as the solid solution in the silicate and liquid phases; (2) when the CaO/SiO2 mole ratio is not large enough,C3 S (tricalcium silicate) in the original steel slag is resolved into C2 S (dicalcium silicate) in the modification process; (3) no C3 S generates even when the CaO/SiO2 mole ratio reaches 3 because CaO primarily reacts with high-content iron; (4) only when the iron reacts completely,may the redundant CaO react with C2 S to produce C3 S; and (5) both the stability and the cementitious activity of the steel slag significantly improve after the modification by lime.
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