收稿日期: 2013-09-17
网络出版日期: 2014-02-19
基金资助
国家自然科学基金资助项目(31130042, 21076086);国家 “十二五” 科技支撑项目(2012BAD37B01);华南理工大学中央高校基本科研业务费专项资金资助项目 (2014ZB0006);中国博士后科学基金资助项目(2014M552204)
Compatibility and Non- Isothermal Crystallization Behavior of Fractionated Palm Oil
Received date: 2013-09-17
Online published: 2014-02-19
Supported by
国家自然科学基金资助项目(31130042, 21076086);国家 “十二五” 科技支撑项目(2012BAD37B01);华南理工大学中央高校基本科研业务费专项资金资助项目 (2014ZB0006);中国博士后科学基金资助项目(2014M552204)
张霞 李琳 谢贺 苏健裕 徐振波 刘国琴 李冰 . 分提棕榈油的相容性及非等温结晶行为[J]. 华南理工大学学报(自然科学版), 2014 , 42(3) : 117 -124 . DOI: 10.3969/j.issn.1000-565X.2014.03.019
The compatibility and non- isothermal crystallization of fractionated palm oil greatly affect the quality offractionated palm oil- based plastic oils.For better application of fractionated palm oil,the compatibility of theblends of palm stearin (44℃) and palmitin (24℃) was studied by means of pulsed nuclear magnetic resonanceand isothermal crystallization curves,and the non- isothermal crystallization behavior of the blends was investigatedvia differential scanning calorimetry.The results show that the binary system of palm stearin and palmitin is of goodcompatibility and forms a eutectic mixture only when the palm stearin proportion and the temperature are respective-ly higher than 50% and 33.3℃. Moreover,it is found that,during the non- isothermal crystallization of theblends,the exothermic peak broadens and the peak temperature increases with the palm stearin proportion at a con-stant cooling rate,and that the enthalpy variation increases with the cooling rate when the palm stearin proportionkeeps constant.
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