化学化工

木质素改性产物的吸附与分散性能

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  • 1. 华南理工大学 化学与化工学院,广东 广州510640; 2. 华南理工大学 制浆造纸工程国家重点实验室,广东 广州510640
邓永红(1969-),女,博士,副教授,主要从事天然高分子溶液行为及自组装研究.Email:yhdeng@scut.edu.cn

收稿日期: 2014-01-27

  修回日期: 2014-07-03

  网络出版日期: 2014-10-01

基金资助

国家自然科学基金资助项目 (21374032,21376100);国家“973”计划项目 (2012CB215302)

Adsorption and Dispersion Performance of Modified Lignin

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  • 1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640,Guangdong,China;   2. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China
邓永红(1969-),女,博士,副教授,主要从事天然高分子溶液行为及自组装研究.Email:yhdeng@scut.edu.cn

Received date: 2014-01-27

  Revised date: 2014-07-03

  Online published: 2014-10-01

Supported by

国家自然科学基金资助项目 (21374032,21376100);国家“973”计划项目 (2012CB215302)

摘要

为了研究木质素改性产物(GCL1-JB)的结构对其分散稳定性及吸附特性的影响,通过向GCL1-JB水溶液中添加二氧六环制备一系列不同构象的GCL1-JB模型。利用分散稳定仪和逐层自组装技术研究不同构象GCL1-JB对水泥的分散稳定性及其吸附特性,发现GCL1-JB的构象越伸展,吸附量越小,但对水泥的分散稳定性更好。GCL1-JB构象较伸展时,能平坦地吸附在固体表面,形成致密平整的吸附膜,有效阻止水泥颗粒间的相互凝聚。这也是GCL1-JB分散稳定性优于木质素磺酸钠的重要原因。

本文引用格式

邓永红 郭运清 邱学青 楼宏铭 . 木质素改性产物的吸附与分散性能[J]. 华南理工大学学报(自然科学版), 2014 , 42(10) : 63 -69 . DOI: 10.3969/j.issn.1000-565X.2014.10.011

Abstract

In order to reveal the influence of the structure of the modified lignin GCL1-JB on its adsorption characteristics and dispersion stability, a series of GCL1-JB of different conformations were prepared by adding dioxane into the aqueous solution of GCL1-JB. Then, the dispersion stability of cement/GCL1-JB suspension and the adsorption characteristics of GCL1-JB of different conformations were determined by using a TurbiscanLab analyzer and by means of the sequential adsorption process. The results show that with the increase of the stretch conformation of GCL1-JB, the amount of GCL1-JB adsorbed on a solid surface decreases while the dispersion stability of GCL1-JB for cement particles increases. In addition, the GCL1-JB of more stretch conformation can adsorb flat  and forms a compact and smooth film, thus effectively preventing cement particles from agglomerating. This is why the dispersion stability of GCL1-JB is superior to that of sodium lignosulfonate.

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