收稿日期: 2013-07-19
修回日期: 2013-11-08
网络出版日期: 2014-01-02
基金资助
国家 “973” 计划项目(2010CB732205); 华南理工大学制浆造纸工程国家重点实验室开放基金资助项目(201356)
Comparison of ECF Short- Sequence Bleaching Processes for Bagasse Pulp
Received date: 2013-07-19
Revised date: 2013-11-08
Online published: 2014-01-02
Supported by
国家 “973” 计划项目(2010CB732205); 华南理工大学制浆造纸工程国家重点实验室开放基金资助项目(201356)
李军 何水淋 李智 徐峻 莫立焕 . 蔗渣浆 ECF 短序漂白流程的对比[J]. 华南理工大学学报(自然科学版), 2014 , 42(2) : 14 -20 . DOI: 10.3969/j.issn.1000-565X.2014.02.003
In this paper,first,three typical element chlorine- free (ECF) short- sequence bleaching processes,namely D0 EpD,OpDEp and OpD,were comparatively investigated.Then,the difference in delignification rate be-tween the chlorine dioxide delignification (D0 ) and the peroxide- reinforced oxygen delignification (Op) was re-vealed,and the effect of pre- delignification on the subsequent bleaching was analyzed.Finally,the AOX (Absor-bable Organic Halides) emission and the direct chemical cost during the bleaching were discussed.The results in-dicate that (1) D0 possesses high delignification selectivity; for instance,the delignification rate reaches 40% at aClO2 dosage of only 0.8% and continuously increases with ClO2 dosage; (2) Op can not only delignify the residuallignin in pulp but also remarkably improve the pulp brightness to a value much higher than that of D0 pulp; (3)OpDEp bleaching is more effective than D0 EpD bleaching at the same chemical dosage in the subsequent bleachingbecause it may result in higher pulp brightness; (4) the final brightness of OpDEp bleached pulp is about 12 per-centage points higher than that of OpD bleached pulp; and (5) at the same pulp brightness,the AOX emitted du-ring the OpDEp bleaching is only about half of that emitted during the D0 EpD bleaching,and the direct chemicalcost of OpDEp bleached pulp is 40. 00 Yuan/t lower than that of D0 EpD bleached pulp,which means that OpDEpbleaching is of higher environmental and economic benefits.
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