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蔗渣浆 ECF 短序漂白流程的对比

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  • 华南理工大学 制浆造纸工程国家重点实验室,广东 广州 510640
李军(1972-),男,博士,教授,主要从事纸浆清洁漂白技术与装备研究.E-mail:ppjunli@scut.edu.cn

收稿日期: 2013-07-19

  修回日期: 2013-11-08

  网络出版日期: 2014-01-02

基金资助

国家 “973” 计划项目(2010CB732205); 华南理工大学制浆造纸工程国家重点实验室开放基金资助项目(201356)

Comparison of ECF Short- Sequence Bleaching Processes for Bagasse Pulp

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  • State Key Laboratory of Pulp and Paper Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China
李军(1972-),男,博士,教授,主要从事纸浆清洁漂白技术与装备研究.E-mail:ppjunli@scut.edu.cn

Received date: 2013-07-19

  Revised date: 2013-11-08

  Online published: 2014-01-02

Supported by

国家 “973” 计划项目(2010CB732205); 华南理工大学制浆造纸工程国家重点实验室开放基金资助项目(201356)

摘要

对典型的蔗渣浆无元素氯( ECF) 短序漂白流程 D0 EpD、OpDEp 及 OpD 进行了对比,探讨了二氧化氯脱木素( D0 ) 与过氧化氢强化氧脱木素( Op) 的脱木素效率差异及对后续漂白的影响,并分析了漂白过程中可吸附有机卤化物( AOX) 的产生量和各漂白流程的直接化学品成本.结果表明: D0 段脱木素选择性好,ClO2 用量为 0.8% 时脱木素率即达40%以上,且用量越高脱木素作用越强; Op 段在脱出纸浆中残余木素的同时能大幅提升纸浆白度,纸浆白度明显高于 D0 浆; 相同后续漂白化学品用量下,OpDEp 漂后浆白度高于 D0 EpD 漂后浆白度, 且比 OpD 漂后浆白度约高 12 个百分点; 相同纸浆白度下,OpDEp漂白过程中产生的可吸附有机卤化物总量约为 D0 EpD 的50%, 其直接化学品成本比后者低约 40. 00 元/t,具有更好的环境、经济效益.

本文引用格式

李军 何水淋 李智 徐峻 莫立焕 . 蔗渣浆 ECF 短序漂白流程的对比[J]. 华南理工大学学报(自然科学版), 2014 , 42(2) : 14 -20 . DOI: 10.3969/j.issn.1000-565X.2014.02.003

Abstract

In this paper,first,three typical element chlorine- free (ECF) short- sequence bleaching processes,namely D0 EpD,OpDEp and OpD,were comparatively investigated.Then,the difference in delignification rate be-tween the chlorine dioxide delignification (D0 ) and the peroxide- reinforced oxygen delignification (Op) was re-vealed,and the effect of pre- delignification on the subsequent bleaching was analyzed.Finally,the AOX (Absor-bable Organic Halides) emission and the direct chemical cost during the bleaching were discussed.The results in-dicate that (1) D0 possesses high delignification selectivity; for instance,the delignification rate reaches 40% at aClO2 dosage of only 0.8% and continuously increases with ClO2 dosage; (2) Op can not only delignify the residuallignin in pulp but also remarkably improve the pulp brightness to a value much higher than that of D0 pulp; (3)OpDEp bleaching is more effective than D0 EpD bleaching at the same chemical dosage in the subsequent bleachingbecause it may result in higher pulp brightness; (4) the final brightness of OpDEp bleached pulp is about 12 per-centage points higher than that of OpD bleached pulp; and (5) at the same pulp brightness,the AOX emitted du-ring the OpDEp bleaching is only about half of that emitted during the D0 EpD bleaching,and the direct chemicalcost of OpDEp bleached pulp is 40. 00 Yuan/t lower than that of D0 EpD bleached pulp,which means that OpDEpbleaching is of higher environmental and economic benefits.

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