化学化工

竹浆木质素高效分散剂在酚水水煤浆中的应用

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  • 华南理工大学化 学与化工学院,广东 广州 510640
杨东杰(1966-),女,博士,教授,主要从事木质素资源化利用的应用基础研究.

收稿日期: 2013-10-11

  修回日期: 2013-12-05

  网络出版日期: 2014-01-02

基金资助

国家国际科技合作专项项目(2013DFA41670);国家杰出青年科学基金资助项目(20925622);国家自然科学基金资助项目(21176096)

Application of High- Efficiency Bamboo Lignin- Based Dispersant to Coal Phenol- Water Slurry

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  • School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China
杨东杰(1966-),女,博士,教授,主要从事木质素资源化利用的应用基础研究.

Received date: 2013-10-11

  Revised date: 2013-12-05

  Online published: 2014-01-02

Supported by

国家国际科技合作专项项目(2013DFA41670);国家杰出青年科学基金资助项目(20925622);国家自然科学基金资助项目(21176096)

摘要

以竹浆造纸黑液为原料制备了竹浆木质素高效分散剂,并应用于酚水水煤浆的制浆; 研究了竹浆木质素高效分散剂的相对分子质量和磺化度对水煤浆浆体流动性的影响,并进一步研究了助剂种类及掺量、分散剂掺量和制浆温度对酚水水煤浆制浆性能和稳定性能的影响.结果表明: 具有中等相对分子质量和中等磺化度的分散剂制浆性能较优,分散降黏作用优于 FDN; 三聚磷酸钠与木质素分散剂复合使用可以降低水煤浆浆体的表观黏度,但加入量过高降黏效果变差,加入量为15% 时,分散降黏效能最好; 随着木质素分散剂掺量的增大,酚水水煤浆的表观黏度不断减小; 随着制浆温度的升高,酚水水煤浆的表观黏度先减小后增大,在温度为 55℃时,分散剂的降黏效果最优,浆体的表观黏度最小; 木质素分散剂掺量为 0.75%时,其分散降黏性能最优,此时水煤浆的稳定性最好.

本文引用格式

杨东杰 李旭昭 李会景 江红艳 李琼 . 竹浆木质素高效分散剂在酚水水煤浆中的应用[J]. 华南理工大学学报(自然科学版), 2014 , 42(2) : 1 -7 . DOI: 10.3969/j.issn.1000-565X.2014.02.001

Abstract

A series of high- efficiency bamboo lignin- based dispersants for the pulping of coal phenol- water slurrywere prepared by using bamboo black liquor as the main raw material. Then,the influences of relative molecularmass and sulfonation degree of the dispersant on the slurry fluidity were investigated. Furthermore, the effects of thetype and dosage of additive,the dispersant do- sage and the pulping temperature on the pulping performance and thestability properties of coal phenol- water slurry were discussed.The results indicate that (1) as compared withFDN,the dispersant with moderate sulfonation degree and medium relative molecular mass possesses better pulpingperformance in reducing the viscosity of coal phenol- water slurry; (2) the combination of sodium tripolyphosphateand the dispersant may reduce the apparent viscosity of the slurry and 15% is a suitable dosage of sodium tri-polyphosphate; (3) the apparent viscosity of the slurry continuously decreases with the increase of dispersant do-sage; (4) with the increase of pulping temperature,the apparent viscosity of the slurry first decreases and then in-creases,with its minimum occurring at 55℃; and (5) coal phenol- water slurry shows best stability properties atthe optimal dispersant dosage of 0.75%.

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