收稿日期: 2013-06-14
修回日期: 2013-11-24
网络出版日期: 2014-04-01
基金资助
国家水体污染控制与治理科技重大专项(2012ZX07403-001);国家自然科学基金资助项目(51178321);高等学校博士学科点专项科研基金资助项目(20120072110050)
Characteristics of Disinfection By- Products Formation from Algae Organic Matters in the Process of Chlorination
Received date: 2013-06-14
Revised date: 2013-11-24
Online published: 2014-04-01
Supported by
国家水体污染控制与治理科技重大专项(2012ZX07403-001);国家自然科学基金资助项目(51178321);高等学校博士学科点专项科研基金资助项目(20120072110050)
高乃云 朱明秋 周石庆 黎雷 戎文磊 周圣东 陆纳新 . 藻源型有机物氯化消毒副产物的生成特性[J]. 华南理工大学学报(自然科学版), 2014 , 42(5) : 48 -53 . DOI: 10.3969/j.issn.1000-565X.2014.05.008
Six kinds of nitrogen- enriched intracellular and extracellular algae organic matters of Microcystic aerugi-nosa with different characteristics were obtained via the fractionation electrodialysis of hydrophilic and hydrophobiccomponents,with the mass concentrations of dissolved organic nitrogen (DON) ranging from 0.57 to 1.69 mg/L.Then,the 3D fluorescence spectrography was adopted to analyze the composition of hydrophilic and hydrophobiccomponents,finding that the former was mainly composed of humus- like substances and the latter mainly composedof protein.Afterwards,the formation characteristics of carbonaceous (nitrogenous) disinfection byproducts fromdifferent organic matters were analyzed and compared after a 3- day chlorination.The results show that (1) hydro-phobic intracellular and extracellular organic matters are of maximum trihalide methane formation potential,espe-cially for chloroform; (2) there is a significant correlation between haloketone formation potential and intracellularand extracellular organic matters; (3) the hydrophilic component in intracellular organic matters is of the greatestnitrogenous disinfection by- products formation potential (DBPFP); (4) the disinfection by- products formation po-tential of each component is not only determined by the value of DOC/DON (namely the mass concentration ratio ofdissolved organic carbon to DON) but also by the characteristics of DON; (5) the DBPFP of extracellular organicmatters is positively correlated with the content of aromatic organic materials,while that of intracellular organic mat-ters is mainly influenced by the properties of aromatic organic materials; and (6) the disinfection by- products pro-duced by extracellular organic matters are in a content order of hydrophobic by- products > hydrophilic by- products> transphilic by- products,while those produced by intracellular matters are indicative of the following order: hy-drophilic by- products > hydrophobic by- products > transphilic by- products.
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