收稿日期: 2013-03-18
修回日期: 2013-08-21
网络出版日期: 2013-11-19
基金资助
国家 “973” 计划项目(2011CB201500);中国博士后科学基金资助项目(2013M531845);广东省科技计划项目(2012B091000166);广州市重大科技专项计划项目(2008A1- D0011)
Investigation into Co- Combustion Kinetics of Paper Mill Sludge and Straw via Thermogravimetric Analysis
Received date: 2013-03-18
Revised date: 2013-08-21
Online published: 2013-11-19
Supported by
国家 “973” 计划项目(2011CB201500);中国博士后科学基金资助项目(2013M531845);广东省科技计划项目(2012B091000166);广州市重大科技专项计划项目(2008A1- D0011)
李玉忠 马晓茜 谢泽琼 蔡梓林 . 造纸污泥与稻草混烧动力学的热重分析法研究[J]. 华南理工大学学报(自然科学版), 2013 , 41(12) : 12 -17 . DOI: 10.3969/j.issn.1000-565X.2013.12.003
In this paper,the combustion characteristics and the kinetics of paper mill sludge,straw and their mix-ture were investigated by means of comprehensive thermogravimetric analysis.The results indicate that (1) thereexist three obvious weightlessness peaks in the combustion curve of paper mill sludge,which correspond to themoisture exhalation,the combustion and exhalation of different volatiles,and the combustion of a small amount offixed carbon and nonflammable organic matters; (2) the ignition temperature of paper mill sludge is only 5.1 ℃higher than that of straw; (3) the addition of straw in the sludge has little effect on the ignition characteristics butsignificantly decreases the burnout temperature of the sludge; (4) the activation energies of sludge and straw firstdecrease and then increase with the increase of conversion rate,and vary in the ranges of 97.0 ~203.7kJ/mol and132.6 ~253.0kJ/mol,respectively; and (5) the average activation energy of the mixture of paper mill sludge andstraw does not monotonically increase with the dosage of paper mill sludge.
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