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TEMPO 氧化浆特性及其对成纸性能的影响

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  • 华南理工大学 制浆造纸工程国家重点实验室,广东 广州 510640
陈港(1967-),男,教授,主要从事特种纸与功能纸制品研究.

收稿日期: 2013-05-16

  修回日期: 2013-06-19

  网络出版日期: 2013-09-03

基金资助

国家 “973” 计划项目(2010CB732206);教育部新世纪人才支持计划项目(D08001Ⅲ)

Properties of TEMPO- Oxidized Wood Fiber and Its Effects on Paper Properties

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  • State Key Laboratory of Pulp and Paper Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China
陈港(1967-),男,教授,主要从事特种纸与功能纸制品研究.

Received date: 2013-05-16

  Revised date: 2013-06-19

  Online published: 2013-09-03

Supported by

国家 “973” 计划项目(2010CB732206);教育部新世纪人才支持计划项目(D08001Ⅲ)

摘要

以蝴蝶桉木纤维为原料,使用2,2,6,6 -四甲基哌啶-1- 氧化物自由基( TEMPO) /溴化钠( NaBr) /次氯酸钠( NaClO) 氧化体系对纤维进行氧化,通过纤维质量分析仪、动态滤水仪和显微镜等对氧化前后纤维的形态和浆料性能进行表征; 并将氧化后的浆料用于制备透明纸,研究了NaClO 用量对纸页性能的影响.结果表明: TEMPO 和 NaBr 用量一定时,随着NaClO 用量的增加,纤维的平均长度减小了0. 8mm,平均宽度增大了4.7μm,细小纤维含量增加 8 倍,纤维的卷曲指数值下降13.9 个百分点,滤水性能变差; 相比于原浆制备的透明纸,氧化浆制备的透明纸强度和弹性模量均增大,抗张指数最大可提高 4 倍,弹性模量最大可提高 6 倍,纸页表面粗糙度最大可降低73.0 %, 透明度高达 87 %.

本文引用格式

陈港 陈青霞 . TEMPO 氧化浆特性及其对成纸性能的影响[J]. 华南理工大学学报(自然科学版), 2013 , 41(10) : 7 -12,19 . DOI: 10.3969/j.issn.1000-565X.2013.10.002

Abstract

In the investigation,the wood fibers from butterfly eucalyptus were oxidized in the 2,2,6,6- tetrameth-ylpiperidine-1- oxyradical (TEMPO) / NaBr/ NaClO oxidization system,and the morphologies and properties of the wood fibers before and after oxidation were characterized by using a fiber quality analyzer (FS300),a dynamic drainage jar (DDJ) and an optical microscope.Then,the oxidized fibers were used to prepare the transparent pa-per,and the effects of the NaClO dosage on the paper properties were discussed.The results show that (1) the in-crease of the NaClO dosage with constant TEMPO and NaBr dosages causes an average fiber length decrease of 0.38mm,an average fiber width increase of 4.7μm,a fine fiber content increase of 8 times and a fiber curl value decrease of 13.9 percentage points as well as a poor pulp drainage property; and (2) as compared with the transparent paper from the wood fibers without the TEMPO treatment,that with the TEMPO treatment achieves a higher tensile strength and a greater elastic modulus with a 5 times tensile index,a 7 times elastic modulus and a 27.0% surface roughness as well as a transparency of 87%.

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