收稿日期: 2013-04-24
修回日期: 2013-06-04
网络出版日期: 2013-09-03
基金资助
NSFC - 广东省人民政府自然科学联合基金资助项目( U1201242) ; 教育部新世纪优秀人才支持计划项目( NCET-11-0152) ; 广州市珠江科技新星专项( 2011J2200058)
Mechanical and Rheological Properties of Polybutylene Succinate / Epoxidized Soybean Oil Blends
Received date: 2013-04-24
Revised date: 2013-06-04
Online published: 2013-09-03
Supported by
NSFC - 广东省人民政府自然科学联合基金资助项目( U1201242) ; 教育部新世纪优秀人才支持计划项目( NCET-11-0152) ; 广州市珠江科技新星专项( 2011J2200058)
赵永青 陈福泉 吴正环 冯彦洪 晋刚 瞿金平 . PBS /ESO 共混物的力学和流变学性能[J]. 华南理工大学学报(自然科学版), 2013 , 41(10) : 103 -107,116 . DOI: 10.3969/j.issn.1000-565X.2013.10.017
In the investigation,the melt blending of polybutylene succinate ( PBS) and a novel plasticizer epoxidizedsoybean oil ( ESO) was carried out by using an internal mixer,and a series of PBS /ESO blends were thusprepared.Moreover,the effects of the ESO content on the mechanical and rheological properties of PBS /ESOblends as well as on their morphologies were discussed.The results show that ( 1) the introduction of the ESO significantlyimproves the tensile and impact toughness of the PBS; ( 2) with the increase of the ESO content,theelongation-at-break and the impact strength of the PBS /ESO blends first increase and then decrease,and at the ESOcontent of 5%,they both reach the maximums which are respectively 15.0 and 1,4 times those of PBS; ( 3) thetensile strength,tensile modulus,flexural strength,and flexural modulus of the PBS /ESO blends decrease with theincrease of the ESO content; ( 4) the addition of ESO significantly decrease the complex viscosity of the moltenPBS,thus resulting in an earlier shear-thinning transition of PBS; and ( 5) the PBS /ESO blend with a higher ESOcontent exhibits a distinct phase separation,which indicates that the ESO/PBS blend is a partially miscible system.
/
| 〈 |
|
〉 |