材料科学与技术

PBS /ESO 共混物的力学和流变学性能

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  • 华南理工大学 聚合物新型成型装备国家工程中心∥聚合物成型加工工程教育部重点实验室,广东 广州 510640
赵永青(1982-),男,博士后,主要从事聚合物成型加工技术与理论、淀粉改性等的研究; E-mail:zhaoyongqing389@163.com

收稿日期: 2013-04-24

  修回日期: 2013-06-04

  网络出版日期: 2013-09-03

基金资助

NSFC - 广东省人民政府自然科学联合基金资助项目( U1201242) ; 教育部新世纪优秀人才支持计划项目( NCET-11-0152) ; 广州市珠江科技新星专项( 2011J2200058)

Mechanical and Rheological Properties of Polybutylene Succinate / Epoxidized Soybean Oil Blends

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  • National Engineering Research Center of Novel Equipment for Polymer Processing∥Key Laboratory of Polymer ProcessingEngineering of the Ministry of Education,South China University of Technology,Guangzhou 510640,Guangdong,China
赵永青(1982-),男,博士后,主要从事聚合物成型加工技术与理论、淀粉改性等的研究; E-mail:zhaoyongqing389@163.com

Received date: 2013-04-24

  Revised date: 2013-06-04

  Online published: 2013-09-03

Supported by

NSFC - 广东省人民政府自然科学联合基金资助项目( U1201242) ; 教育部新世纪优秀人才支持计划项目( NCET-11-0152) ; 广州市珠江科技新星专项( 2011J2200058)

摘要

将新型增塑剂环氧大豆油( ESO) 与聚丁二酸丁二醇酯( PBS) 进行熔融共混,制得PBS /ESO 共混物,研究了ESO 含量对PBS 力学、流变学性能以及相形态的影响. 结果表明: ESO 可显著提高PBS 的韧性; 随ESO 含量增加,共混物的断裂伸长率、冲击强度先增大后减小,在ESO 含量为5. 0%时达到最大值,分别为PBS 的15. 0 倍和1. 4 倍,共混物的拉伸强度、拉伸模量、弯曲强度、弯曲模量则随之减小; ESO 能明显降低PBS 熔体的黏度,使其在更低的角频率下呈现出剪切变稀的流变行为; ESO 与PBS 是部分相容的,较高ESO 含量的共混物会发生明显的相分离现象.

本文引用格式

赵永青 陈福泉 吴正环 冯彦洪 晋刚 瞿金平 . PBS /ESO 共混物的力学和流变学性能[J]. 华南理工大学学报(自然科学版), 2013 , 41(10) : 103 -107,116 . DOI: 10.3969/j.issn.1000-565X.2013.10.017

Abstract

In the investigation,the melt blending of polybutylene succinate ( PBS) and a novel plasticizer epoxidizedsoybean oil ( ESO) was carried out by using an internal mixer,and a series of PBS /ESO blends were thusprepared.Moreover,the effects of the ESO content on the mechanical and rheological properties of PBS /ESOblends as well as on their morphologies were discussed.The results show that ( 1) the introduction of the ESO significantlyimproves the tensile and impact toughness of the PBS; ( 2) with the increase of the ESO content,theelongation-at-break and the impact strength of the PBS /ESO blends first increase and then decrease,and at the ESOcontent of 5%,they both reach the maximums which are respectively 15.0 and 1,4 times those of PBS; ( 3) thetensile strength,tensile modulus,flexural strength,and flexural modulus of the PBS /ESO blends decrease with theincrease of the ESO content; ( 4) the addition of ESO significantly decrease the complex viscosity of the moltenPBS,thus resulting in an earlier shear-thinning transition of PBS; and ( 5) the PBS /ESO blend with a higher ESOcontent exhibits a distinct phase separation,which indicates that the ESO/PBS blend is a partially miscible system.

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