材料科学与技术

有机蒙脱土/废胶粉复合改性沥青的性能

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  • 华南理工大学 化学与化工学院,广东 广州 510640
肖新颜(1964-),男,教授,博士生导师,主要从事聚合物纳米复合材料研究.

收稿日期: 2012-12-19

  修回日期: 2013-01-22

  网络出版日期: 2013-05-03

基金资助

石油化工联合基金资助项目(U1162120)

Properties of Organic Montmorillonite/Crumb Rubber Compound Modified Asphalt

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  • School of Chemistry and Chemical Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China
肖新颜(1964-),男,教授,博士生导师,主要从事聚合物纳米复合材料研究.

Received date: 2012-12-19

  Revised date: 2013-01-22

  Online published: 2013-05-03

Supported by

石油化工联合基金资助项目(U1162120)

摘要

采用熔融共混法制备了有机蒙脱土( OMMT) /废胶粉复合改性沥青,通过 X 射线衍射( XRD) 分析和原子力显微镜( AFM) 分析表征了复合改性沥青的微观结构,研究了复合改性沥青的物理性能、抗热氧老化性能和热储存稳定性.结果表明: OMMT 的掺入使废胶粉在沥青中的分散更加均匀,OMMT/废胶粉复合改性沥青形成剥离结构; 与废胶粉改性沥青相比,OMMT/废胶粉复合改性沥青的高温性能得到改善,随着 OMMT 掺量的增加,软化点大幅升高,25℃针入度及5℃延度减小; 与废胶粉改性沥青相比,OMMT/废胶粉复合改性沥青的抗热氧老化性能和热储存稳定性明显提高.

本文引用格式

肖新颜 杨泽清 . 有机蒙脱土/废胶粉复合改性沥青的性能[J]. 华南理工大学学报(自然科学版), 2013 , 41(6) : 116 -120 . DOI: 10.3969/j.issn.1000-565X.2013.06.018

Abstract

Organic montmorillonite (OMMT) /crumb rubber compound modified asphalt was prepared via melt blending,and the microstructure of the product was characterized and analyzed by means of XRD and AFM.More-over,the physical properties,thermal oxidative aging properties and thermal storage stability of the product were in-vestigated.The results show that (1) the dispersion of crumb rubber in the modified asphalt becomes more uniform and an exfoliated structure forms due to the doping of OMMT; (2) as compared with the crumb rubber modified as-phalt,OMMT/crumb rubber compound modified asphalt is of improved high- temperature performances,for in-stance,with the increase of OMMT dosage,the softening point sharply increases,and the penetration (25℃) and the ductility (5℃) both decrease; and (3) after the doping of OMMT,both the thermal oxidative aging properties and the thermal storage stability of the compound modified asphalt improve significantly.

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