华南理工大学学报(自然科学版) ›› 2008, Vol. 36 ›› Issue (12): 52-55.

• 环境科学与技术 • 上一篇    下一篇

介质阻挡等离子体反应器中的甲醛降解

陈砺 代文 严宗诚 王红林 成贝贝   

  1. 华南理工大学 化学与化工学院, 广东 广州 510640
  • 收稿日期:2007-11-29 修回日期:2008-02-26 出版日期:2008-12-25 发布日期:2008-12-25
  • 通信作者: 陈砺(1958-),男,博士,教授,主要从事等离子体化学及生物质能研究. E-mail:celichen@scut.edu.cn
  • 作者简介:陈砺(1958-),男,博士,教授,主要从事等离子体化学及生物质能研究.
  • 基金资助:

    广东省科技计划项目(2005B50101001);广东省一教育部产学研合作项目(2007B090400069)

Degradation of Formaldehyde in Dielectric Barrier Discharge Plasma Reactor

Chen Li  Dai Wen  Yan Zong-cheng  Wang Hong-lin  Cheng Bei-bei   

  1. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, Guangdong, China
  • Received:2007-11-29 Revised:2008-02-26 Online:2008-12-25 Published:2008-12-25
  • Contact: 陈砺(1958-),男,博士,教授,主要从事等离子体化学及生物质能研究. E-mail:celichen@scut.edu.cn
  • About author:陈砺(1958-),男,博士,教授,主要从事等离子体化学及生物质能研究.
  • Supported by:

    广东省科技计划项目(2005B50101001);广东省一教育部产学研合作项目(2007B090400069)

摘要: 考察了甲醛在平板式和管式两种介质阻挡放电(DBD)等离子体反应器中的降解能耗以及两种反应器中放电电压、甲醛初始质量浓度和停留时间对甲醛降解率的影响.结果表明:与管式等离子体反应器相比,平板式反应器的甲醛降解能耗大大降低(从55.0W·h/m3降低至12.8W·h/m3);管式反应器和平板式反应器的甲醛降解率均随着放电电压的升高而增大,并分别在11 kV和18 kV处出现拐点,随后降解率增幅减小;甲醛降解率随初始质量浓度的增加先增大后降低,随停留时间的延长而增大.

关键词: 介质阻挡放电, 等离子体, 甲醛, 降解率, 能耗

Abstract:

This paper deals with the energy consumptions for the formaldehyde discharge (DBD) plasma reactors respectively with tube and flat pIate types. It degradation in two dielectric barrier aims to reveal the influences of discharging voltage, initial formaldehyde mass concentration and residence time on the degradation rate of formaldehyde. Experimental results indicate that (1) the energy consumption in the fiat-plate reactor (12. 8Woh/m3) is far below that of the tube reactor (55.0 Woh/m3 ) ; (2) the degradation rates of formaldehyde in both the tube and the flat-plate reactors greatly increase with the discharging voltage, then the increase degrees become low at the voltages of 11 kV and 18 kV, respectively ; concentration and then decreases, and (3) the degradation rate at first increases with the initial formaldehyde mass but it continuously increases with the extension of the resistance time.

Key words: dielectric barrier discharge, plasma, formaldehyde, degradation rate, energy consumption