华南理工大学学报(自然科学版) ›› 2004, Vol. 32 ›› Issue (6): 45-48,54.

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有机硅氧烷改性水性羟基丙烯酸树脂的研制

潘莉莎 文秀芳 程江 杨卓如   

  1. 华南理工大学化工学院 广东 广州 510640

  • 收稿日期:2003-11-14 出版日期:2004-06-20 发布日期:2015-09-09
  • 通信作者: 潘莎莉(1981-),女,博士生,主要从事精细化学工程研究。 E-mail:happylisap@163.net
  • 作者简介:潘莎莉(1981-),女,博士生,主要从事精细化学工程研究。

Preparation of Water-borne Hydroxyacrylate Resin Grafted by Organic Siloxane

Pan Li-sha Wen Xiu-fang Cheng Jiang Yang Zhuo-ru   

  • Received:2003-11-14 Online:2004-06-20 Published:2015-09-09
  • Contact: 潘莎莉(1981-),女,博士生,主要从事精细化学工程研究。 E-mail:happylisap@163.net
  • About author:潘莎莉(1981-),女,博士生,主要从事精细化学工程研究。

摘要: 在水性羟基丙烯酸树脂的合成中引入有机硅氧烷单体进行改性,以提高水性双组分丙烯酸聚氨酯木器涂料的耐水、耐溶剂等涂膜性能.探讨了树脂配方中丙烯酸酯类单体、有机硅氧烷单体的种类以及树脂酸值、羟基含量、玻璃化温度、中和度等参数对涂料双组分相容性、干燥性能和涂膜性能的影响.研究表明,在合成配方中选择较高活性的丙烯酸羟乙酯单体和阻碍性的乙烯基三异丙氧基硅烷单体,选择酸值在35~50mg/g(以KOH含量计)之间、羟基含量在3.5%左右、玻璃化温度在25℃左右并配合60%左右的中和度,所合成的树脂配制成的木器涂料具有优异的耐水和耐溶剂性,其干燥及胶化时间均达施工要求.

关键词: 有机硅氧烷, 水性涂料, 聚氨酯, 丙烯酸

Abstract: Organic siloxane was added in the synthesis prescription of water-borne hydroxyacrylate resin to improve the performances of water-borne two-component acrylate-polyurethane coating, such as the resistance to water and solvent. The effects of various factors on the consistency of the two components as well as the performance of drying and coating were investigated. These factors include such parameters as the acrylate monomer type, the organic siloxane monomer type, the acid value of the resin, the hydroxy content, the temperature of glass transformation and neutralization degree, etc. The results show that, by choosing high-activity hydroxide acrylate monomer and interruptive vinyltriisopropoxysilane momomer and by controlling the acid value at 35 -50mg/g(calculated in the KOH content) with the hydroxy content set at 3. 5% , the glass transformation temperature set at 25℃ and the neutralization degree at 60% , excellent resin can be synthesized, from which wood coating with excellent resistance to water and solvent can be confected. The drying time and gelling time of the coating meet the construction needs well.

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