华南理工大学学报(自然科学版) ›› 2014, Vol. 42 ›› Issue (6): 40-45.doi: 10.3969/j.issn.1000-565X.2014.06.007

• 材料科学与技术 • 上一篇    下一篇

负压封闭引流用聚乙烯醇缩甲醛的制备及性能

郭森 马天从 邹永昆 刘芳 何经纬   

  1. 华南理工大学 材料科学与工程学院,广东 广州 510640
  • 收稿日期:2013-10-30 修回日期:2013-12-09 出版日期:2014-06-25 发布日期:2014-05-01
  • 通信作者: 何经纬(1982-),男,博士,讲师,主要从事生物医用高分子材料研究. E-mail:msjwhe@scut.edu.cn
  • 作者简介:郭森(1989-),男,博士生,主要从事生物医用高分子材料研究.E-mail:guo0395@126.com
  • 基金资助:

    广东省自然科学基金重点项目(S2011020001452)

Preparation and Properties of Polyvinyl Formal for Vacuum Sealing Drainage

Guo Sen Ma Tian- cong Zou Yong- kun Liu Fang He Jing- wei   

  1. School of Materials Science and Engineering,South China University of Technology,Guangzhou 510640,Guangdong,China
  • Received:2013-10-30 Revised:2013-12-09 Online:2014-06-25 Published:2014-05-01
  • Contact: 何经纬(1982-),男,博士,讲师,主要从事生物医用高分子材料研究. E-mail:msjwhe@scut.edu.cn
  • About author:郭森(1989-),男,博士生,主要从事生物医用高分子材料研究.E-mail:guo0395@126.com
  • Supported by:

    广东省自然科学基金重点项目(S2011020001452)

摘要: 采用机械搅拌发泡法,以聚乙烯醇、甲醛、淀粉、十二烷基磺酸钠(SDS)和硫酸为原料,制备负压封闭引流用聚乙烯醇缩甲醛泡沫材料,研究了搅拌速率、SDS 用量、固化温度、淀粉添加量等对产品吸水性能、拉伸性能、孔径及其分布的影响.结果表明:SDS 添加量在 0.0 ~2.0g 范围内时,材料吸水性能随 SDS 添加量增大而增大;SDS 添加量大于 1.0g后,材料的力学性能趋于稳定;随着淀粉用量的增大和固化温度的升高,材料的力学性能急剧下降;高速搅拌可以制得孔径更小、孔径分布更均匀的发泡材料;SDS 用量增大会产生更多的大孔,最终产品的孔径分布范围更大;泡孔数目与淀粉添加量并无严格对应关系.

关键词: 负压封闭引流, 聚乙烯醇缩甲醛, 泡沫材料, 吸水性能, 拉伸性能, 孔径, 孔径分布

Abstract:

Polyvinyl formal,a kind of foam material for vacuum sealing drainage,was synthesized via a mechanicalmixing and foaming approach,with polyvinyl alcohol,methanal,starch,sodium dodecyl sulfate (SDS) and sulfu-ric acid as materials.Then,the effects of stirring speed,SDS content,curing temperature and starch dosage on thewater absorbency,tensile property,pore size and pore size distribution of the product were investigated.The resultsshow that (1) the water absorbency of the synthesized foam material increases with the SDS content ranging from 0.0 to 2.0 g; (2) the mechanical properties of the material become stable when SDS content is more than 1.0 gbut dramatically degrade with the increase of starch dosage and curing temperature; (3) higher stirring speed mayresult in smaller pore and more uniform pore size distribution; (4) more SDS may lead to more large pores and wi-der pore size distribution; and (5) the number of pores is not strictly related to starch dosage.

Key words: vacuum sealing drainage, polyvinyl formal, foam material, water absorbency, tensile property, pore size, pore size distribution

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