华南理工大学学报(自然科学版) ›› 2007, Vol. 35 ›› Issue (10): 37-43.

• 创刊五十周年纪念专辑 • 上一篇    下一篇

机械合金化制备的Al 基轴承合金的结构与性能

朱敏 曾美琴 欧阳柳章 吴志方 刘辛   

  1. 华南理工大学 机械工程学院,广东 广州 510640
  • 收稿日期:2007-04-11 出版日期:2007-10-25 发布日期:2007-10-25
  • 通信作者: 朱敏(1962-) ,男,教授,博士生导师,主要从事金属材料的研究. E-mail:memzhu@scut. edu.cn
  • 作者简介:朱敏(1962-) ,男,教授,博士生导师,主要从事金属材料的研究.
  • 基金资助:

    国家自然科学基金资助项目(50371027) ;广东省自然科学基金团队项目

Microstructure and Wear Properties of AI-Based Bearing AlIoys Fabricated by Mechanical AIIoying

Zhu Min  Zeng Mei-qin  Ouyang Liu-zhang  Wu Zhi-fang  Liu Xin   

  1. School of Mechanical Engineering , South China Univ. of Tech. , Guangzhou 510640 , Guangdong , China
  • Received:2007-04-11 Online:2007-10-25 Published:2007-10-25
  • Contact: 朱敏(1962-) ,男,教授,博士生导师,主要从事金属材料的研究. E-mail:memzhu@scut. edu.cn
  • About author:朱敏(1962-) ,男,教授,博士生导师,主要从事金属材料的研究.
  • Supported by:

    国家自然科学基金资助项目(50371027) ;广东省自然科学基金团队项目

摘要: 采用机械合金化方法制备AI-Pb 和Al-Sn 基合金粉末,然后通过烧结将之制备成合金.采用XRD 、SEM 、TEM 分析技术对合金的微观结构进行表征,结果表明在适当机械合金化和烧结工艺条件下,可得到Al 基体上均匀分布尺寸约为100nm 的软相Pb 或Sn的合金.摩擦摩损性能测试表明,这种组织结构的Al 基轴承合金具有优良的性能.对Pb相粗化的研究表明,这种纳米复合结构具有较好的稳定性,其第二相的长大仍然满足关于粗化的经典理论一-LSW 理论.研究中还特别关注了机械合金化过程中的污染对Al 基轴承合金组织结构的影响,友现铁污染会导致Al7 Cu2 Fe 相的生成,氧污染则导致Pb 颗粒上有Al2 O3 附着.

关键词: 机械合金化, Al 基轴承合金, 纳米复合结构, 摩擦摩损性能

Abstract:

AI-Pb and AI-Sn bearing alloys were obtained by sintering the AI-Pb and AI-Sn powder mixtures preparedvia mechanical alloying. According to the microstructures of the alloys characterized by means of XRD , SEMand TEM , the Pb or Sn soft phase in a size of about 100 nm homogeneously disperses in AI matrix of the alloys fabricatedunder appropriate mechanical alloying and sintering conditions. It is indicated by the wear test that the AIbasedbearing alloys containing nano-sized Pb or Sn dispersoids are of excellent wear properties. Moreover , accordingto the coarsening behavior of the nanophase particles , the nano-composite structure possesses good stability andthe growth of the second phase still follows the classical ripening theoηdescribed by LSW equation. As for theeffect of the contamination induced by milling on the microstructure of Al-based bearing alloys , the Al7 Cu2 Fe phaseforms owing to the Fe contamination , and the adherence of nano-sized Al2 O3  phase to Pb particles occurs due to theoxygen contammatlOn.

Key words: mechanical alloying, Al-based bearing alloy, nano-composite structure, wear property